Stable salts of heteroleptic iron carbonyl/nitrosyl cations
Abstract: The oxidation of Fe(CO)5 with the [NO]+ salt of the weakly coordinating perfluoroalkoxyaluminate anion [F‐{Al(ORF)3}2]− (RF=C(CF3)3) leads to stable salts of the 18 valence electron (VE) species [Fe(CO)4(NO)]+ and [Fe(CO)(NO)3]+ with the Enemark–Feltham numbers of {FeNO}8 and {FeNO}10. This finally concludes the triad of heteroleptic iron carbonyl/nitrosyl complexes, since the first discovery of the anionic ([Fe(CO)3(NO)]−) and neutral ([Fe(CO)2(NO)2]) species over 80 years ago. Both complexes were fully characterized (IR, Raman, NMR, UV/Vis, scXRD, pXRD) and are stable at room temperature under inert conditions over months and may serve as useful starting materials for further investigations
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Notes
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Angewandte Chemie. International edition. - 59, 14 (2020) , 5581-5585, ISSN: 1521-3773
- Classification
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Chemie
- Keyword
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Carbonylverbindungen
Eisen
Stickstoffoxide
Schwingungsspektroskopie
- Event
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Veröffentlichung
- (where)
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Freiburg
- (who)
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Universität
- (when)
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2020
- Creator
- DOI
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10.1002/anie.201915942
- URN
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urn:nbn:de:bsz:25-freidok-1552332
- Rights
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Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:48 AM CEST
Data provider
This object is provided by:
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Bohnenberger, Jan
- Krossing, Ingo
- Universität
Time of origin
- 2020
Other Objects (12)
Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations
Stabile Salze heteroleptischer Eisen‐Carbonyl/Nitrosylkationen
Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations
The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions
From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations
Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide
Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett
Stabile Salze heteroleptischer Eisen‐Carbonyl/Nitrosylkationen
Investigation of novel transition metal carbonyl cations and dinitrogen complexes
Synthesis and Characterization of a Stable Nickelocenium Dication Salt
Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides
Synthesis and Structural Characterization of Gallium (I) and Indium (I) Cations Coordinated by Pentamethylethylenediamine
Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations
Stabile Salze heteroleptischer Eisen‐Carbonyl/Nitrosylkationen
Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations
The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions
From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations
Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide
Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett
Stabile Salze heteroleptischer Eisen‐Carbonyl/Nitrosylkationen
Investigation of novel transition metal carbonyl cations and dinitrogen complexes
Synthesis and Characterization of a Stable Nickelocenium Dication Salt
Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides
Synthesis and Structural Characterization of Gallium (I) and Indium (I) Cations Coordinated by Pentamethylethylenediamine
Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations
Stabile Salze heteroleptischer Eisen‐Carbonyl/Nitrosylkationen
Synthesis of novel homoleptic and heteroleptic transition metal carbonyl and nitrosyl cations
The synthesis of reactive gold(I) and phosphorus cations with nitrosyl salts of weakly coordinating anions
From pentacarbonylcobalt(I) salts to piano-stool and sandwich cations
Beiträge zur Chemie des Aluminiums : Synthese, Struktur und Reaktivität monomerer Aminoalane, Additionsverbindungen der Aluminiumhalogenide
Chemie mit schwach koordinierenden Anionen : Synthese einer neuen Klasse schwach koordinierender Anionen des Typs Al(ORF)-4, Lewis-Säure-Base-Addukte der sehr schwachen Lewis-Basen S8, P4 und P4S3 mit dem Ag+-Kation von Ag[Al(ORF)4], von homopolyatomaren Phosphorkationen zu Al(ORF)-4-Salzen neuer binärer Phosphor-Halogen-Kationen mit Polyphosphorskelett
Stabile Salze heteroleptischer Eisen‐Carbonyl/Nitrosylkationen
Investigation of novel transition metal carbonyl cations and dinitrogen complexes
Synthesis and Characterization of a Stable Nickelocenium Dication Salt
Syntheses, characterization and application of a variety of ethylzinc-cations and zinc alkoxides