Matching Carbenes and Sulfoximines via Ketenes Generated from α ‐Diazoketones by Blue Light
Abstract: Although NH‐sulfoximines are known to react with carbenes by deamidation pathways, they can be combined if the latter are generated as transients from diazo compounds under blue light irradiation to undergo rapid Wolff rearrangement to generate reactive ketenes. Subsequent addition of sulfoximines or sulfonimidamides lead to N‐acylated products in good to excellent yields. Beneficial are the mild reaction conditions, which neither require the addition of a base nor an oxidant or a metal catalyst.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Matching Carbenes and Sulfoximines via Ketenes Generated from α ‐Diazoketones by Blue Light ; day:11 ; month:01 ; year:2023 ; extent:7
Advanced synthesis & catalysis ; (11.01.2023) (gesamt 7)
- Creator
- DOI
-
10.1002/adsc.202201274
- URN
-
urn:nbn:de:101:1-2023011214025316080121
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:29 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Pan, Shulei
- Passia, Marco Thomas
- Wang, Xianliang
- Wu, Peng
- Ma, Ding
- Bolm, Carsten
Other Objects (12)
Matching carbenes and sulfoximines via ketenes generated from α-diazoketones by blue light
Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions
Photocatalytic Fluoro Sulfoximidations of Styrenes
Photocatalytic Fluoro Sulfoximidations of Styrenes
Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur
Copper-Catalyzed N-Alkylations of NH-Sulfoximines Under Visible Light
Photocatalytic Fluoro Sulfoximidations of Styrenes
Photocatalytic Fluoro Sulfoximidations of Styrenes
Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides
Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides
Matching carbenes and sulfoximines via ketenes generated from α-diazoketones by blue light
Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions
Photocatalytic Fluoro Sulfoximidations of Styrenes
Photocatalytic Fluoro Sulfoximidations of Styrenes
Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur
Copper-Catalyzed N-Alkylations of NH-Sulfoximines Under Visible Light
Photocatalytic Fluoro Sulfoximidations of Styrenes
Photocatalytic Fluoro Sulfoximidations of Styrenes
Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides
Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides
Matching carbenes and sulfoximines via ketenes generated from α-diazoketones by blue light
Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions
Photocatalytic Fluoro Sulfoximidations of Styrenes
Photocatalytic Fluoro Sulfoximidations of Styrenes
Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur
Copper-Catalyzed N-Alkylations of NH-Sulfoximines Under Visible Light
Photocatalytic Fluoro Sulfoximidations of Styrenes
Photocatalytic Fluoro Sulfoximidations of Styrenes
Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides