Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

to related objects

Abstract: Starting from N‐acyl sulfonimidamides, mechanochemically generated rhodium nitrenoids undergo intramolecular N−O couplings to provide unprecedented 1,3,2,4‐oxathiadiazole 3‐oxides in good to excellent yields. The cyclization proceeds efficiently with a catalyst loading of only 0.5 mol % in the presence of phenyliodine (III) diacetate (PIDA) as oxidant. Neither an inert atmosphere nor additional heating is required in this solvent‐free procedure. Under heat or blue light, the newly formed five‐membered heterocycles function as nitrene precursors reacting with sulfoxides as exemplified by the imidation of dimethyl sulfoxide.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides ; day:09 ; month:11 ; year:2024 ; extent:6
Angewandte Chemie ; (09.11.2024) (gesamt 6)

Creator: Pan, Shulei
Wu, Peng
Bampi, Dimitra
Ward, Jas S.
Rissanen, Kari
Bolm, Carsten

DOI: 10.1002/ange.202413181

URN: urn:nbn:de:101:1-2411101319128.464096974167

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:30 AM CEST

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.

Show original at data provider

Associated

Pan, Shulei
Wu, Peng
Bampi, Dimitra
Ward, Jas S.
Rissanen, Kari
Bolm, Carsten

Other Objects (12)

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N-Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N-Acyl Sulfonimidamides

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions

Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions

Association between meniscal extrusion and disease severity in knee osteoarthritis: a retrospective case-control study

Association between meniscal extrusion and disease severity in knee osteoarthritis: a retrospective case-control study

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Xue sheng yong shu : = Student's book

Xue sheng yong shu : = Student's book

Jiao shi yong shu : = Teacher's book

Jiao shi yong shu : = Teacher's book

A meta-analysis on the potency of foot-and-mouth disease vaccines in different animal models

A meta-analysis on the potency of foot-and-mouth disease vaccines in different animal models

A meta-analysis: the efficacy and effectiveness of polypeptide vaccines protect pigs from foot and mouth disease

A meta-analysis: the efficacy and effectiveness of polypeptide vaccines protect pigs from foot and mouth disease

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N-Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N-Acyl Sulfonimidamides

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions

Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions

Association between meniscal extrusion and disease severity in knee osteoarthritis: a retrospective case-control study

Association between meniscal extrusion and disease severity in knee osteoarthritis: a retrospective case-control study

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Xue sheng yong shu : = Student's book

Xue sheng yong shu : = Student's book

Jiao shi yong shu : = Teacher's book

Jiao shi yong shu : = Teacher's book

A meta-analysis on the potency of foot-and-mouth disease vaccines in different animal models

A meta-analysis on the potency of foot-and-mouth disease vaccines in different animal models

A meta-analysis: the efficacy and effectiveness of polypeptide vaccines protect pigs from foot and mouth disease

A meta-analysis: the efficacy and effectiveness of polypeptide vaccines protect pigs from foot and mouth disease

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N ‐Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N-Acyl Sulfonimidamides

Mechanochemical Conditions for Intramolecular N−O Couplings via Rhodium Nitrenoids Generated from N-Acyl Sulfonimidamides

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions

Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions

Iron-Catalyzed Intramolecular Arene C(sp$_2}$)-H Amidations under Mechanochemical Conditions

Association between meniscal extrusion and disease severity in knee osteoarthritis: a retrospective case-control study

Association between meniscal extrusion and disease severity in knee osteoarthritis: a retrospective case-control study

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

Xue sheng yong shu : = Student's book

Xue sheng yong shu : = Student's book

Jiao shi yong shu : = Teacher's book

Jiao shi yong shu : = Teacher's book

A meta-analysis on the potency of foot-and-mouth disease vaccines in different animal models

A meta-analysis on the potency of foot-and-mouth disease vaccines in different animal models

A meta-analysis: the efficacy and effectiveness of polypeptide vaccines protect pigs from foot and mouth disease

A meta-analysis: the efficacy and effectiveness of polypeptide vaccines protect pigs from foot and mouth disease

Cultural heritage institutions wishing to register will find more information here.

Fields marked * need to be filled in.

Username*

Please enter your username

Email*

Please enter your email address

Please do not fill this field

First name

Last name

Password*

Please enter your password

Confirm password*

Please enter the same password

I have read the terms of use and the privacy policy for the collection of personal data and accept them. *

This field is required.

I would like to subscribe to the newsletter of the Deutsche Digitale Bibliothek. See newsletter subscription info.

Account created

Your "My DDB" account has been successfully created. Before you can log in to your account, you must click the confirmation link in the message we just sent to the email address you provided.