Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

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Abstract: A mechanochemical synthesis of sulfonimidamides by iron (II)‐catalyzed exogenous ligand‐free N‐acyl nitrene transfer to sulfinamides is reported. The one‐step method tolerates a wide range of sulfinamides with various substituents under solvent‐free ambient conditions. Compared to its solution‐phase counterpart, this mechanochemical approach shows better conversion and chemoselectivity. Mechanistic investigations by ESI‐MS revealed the generation of crucial nitrene iron intermediates.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones ; day:21 ; month:12 ; year:2023 ; extent:7
Angewandte Chemie / International edition. International edition ; (21.12.2023) (gesamt 7)

Creator: Pan, Shulei
Mulks, Florian F.
Wu, Peng
Rissanen, Kari
Bolm, Carsten

DOI: 10.1002/anie.202316702

URN: urn:nbn:de:101:1-2023122214165284694179

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:30 AM CEST

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Associated

Pan, Shulei
Mulks, Florian F.
Wu, Peng
Rissanen, Kari
Bolm, Carsten

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Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions: Direct Synthesis of N ‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones

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Azasulfur( iv ) derivatives of sulfite and sulfinate esters by formal S–S bond insertion of dichloramines

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Mechanochemical Mitsunobu Reactions

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