Photocatalytic Fluoro Sulfoximidations of Styrenes
Abstract: Reactions of difluoroiodotoluene with NH‐sulfoximines provide new hypervalent iodine (III) reagents, which photocatalytically transfer a fluoro and a sulfoximidoyl group onto styrenes with high regioselectivity. The substrate scope is broad with respect to both sulfoximines and olefins. Following an operationally simple protocol, a large library of fluorine‐containing N‐functionalized sulfoximines can be accessed. Results from mechanistic investigations revealed the importance of radical intermediates.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Photocatalytic Fluoro Sulfoximidations of Styrenes ; volume:59 ; number:33 ; year:2020 ; pages:14134-14137 ; extent:4
Angewandte Chemie / International edition. International edition ; 59, Heft 33 (2020), 14134-14137 (gesamt 4)
- Creator
- DOI
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10.1002/anie.202005844
- URN
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urn:nbn:de:101:1-2022061212544546984458
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
Data provider
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Wang, Chenyang
- Tu, Yongliang
- Ma, Ding
- Bolm, Carsten
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Iron‐Catalyzed Intramolecular Arene C (sp 2)−H Amidations under Mechanochemical Conditions
Matching Carbenes and Sulfoximines via Ketenes Generated from α ‐Diazoketones by Blue Light
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Chirale Katalysatoren für enantioselektive C-C-Verknüpfungen
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Die Entwicklung der Streitgegenstandslehre in Deutschland und Europa und ihre Vorbildwirkung für das chinesische Recht
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