High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters
Abstract: Doped clusters in the gas phase provide nanoconfined model systems for the study of system-bath interactions. To gain insight into interaction mechanisms between chromophores and their environment, the ensemble inhomogeneity has to be lifted and the homogeneous line profile must be accessed. However, such measurements are very challenging at the low particle densities and low signal levels in cluster beam experiments. Here, we dope cryogenic rare-gas clusters with phthalocyanine molecules and apply action-detected two-dimensional electronic spectroscopy to gain insight into the local molecule-cluster environment for solid and superfluid cluster species. The high-resolution homogeneous linewidth analysis provides a benchmark for the theoretical modelling of binding configurations and shows a promising route for high-resolution molecular two-dimensional spectroscopy
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Notes
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Nature communications. - 13, 1 (2022) , 3350, ISSN: 2041-1723
- Event
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Veröffentlichung
- (where)
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Freiburg
- (who)
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Universität
- (when)
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2022
- Creator
- DOI
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10.1038/s41467-022-31021-z
- URN
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urn:nbn:de:bsz:25-freidok-2276540
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:25 AM CEST
Data provider
This object is provided by:
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Bangert, Ulrich
- Stienkemeier, Frank
- Bruder, Lukas
- Universität
Time of origin
- 2022
Other Objects (12)
High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters
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Vibrational structure and dynamics of triatomic alkali molecules and RbHe exciplexes on helium nanodroplets investigated with femtosecond and picosecond pump-probe techniques : = Vibrationsstruktur und Dynamik von dreiatomigen Alkalimolekülen und RbHe Exziplexen auf Helium Nanotröpfchen, untersucht mit Femtosekunden und Picosekunden Pump-Probe Techniken
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Influence of an atomic resonance on the coherent control of the photoionization process
Phase-modulated coherent time-domain spectroscopy in the extreme ultraviolet regime
Time-resolved photoelectron and photoion spectroscopy of atomic and molecular clusters using XUV radiation
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Effects of high pulse intensity and chirp in two-dimensional electronic spectroscopy of an atomic vapor
High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters
Femtosekundenspektroskopie an dotierten Heliumnanotröpfchen : : dissipative Vibrationsdynamik und Charakterisierung eines Nanoplasmas
Vibrational structure and dynamics of triatomic alkali molecules and RbHe exciplexes on helium nanodroplets investigated with femtosecond and picosecond pump-probe techniques : = Vibrationsstruktur und Dynamik von dreiatomigen Alkalimolekülen und RbHe Exziplexen auf Helium Nanotröpfchen, untersucht mit Femtosekunden und Picosekunden Pump-Probe Techniken
Spektroskopische Untersuchungen an Tetracen und PTCDA-Molekülen eingelagert in Helium-Nanotröpfchen oder auf der Oberfläche von Edelgasclustern Beeinflussung der Fluoreszenzlebensdauer durch kollektive Effekte
Solvation of atoms and molecules and their interactions with rare gas and hydrogen clusters : = Solvatisierung von Atomen und Molekülen und deren Wechselwirkung mit Edelgas- und Wasserstoff-Clustern
Diffraction imaging of light induced dynamics in xenon-doped helium nanodroplets
Spin-state-controlled chemi-ionization reactions between metastable helium atoms and ground-state lithium atoms
Influence of an atomic resonance on the coherent control of the photoionization process
Phase-modulated coherent time-domain spectroscopy in the extreme ultraviolet regime
Time-resolved photoelectron and photoion spectroscopy of atomic and molecular clusters using XUV radiation
Fluorescence lifetime reduction mechanisms of organic complexes studied by cluster isolation spectroscopy
Effects of high pulse intensity and chirp in two-dimensional electronic spectroscopy of an atomic vapor
High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters
Femtosekundenspektroskopie an dotierten Heliumnanotröpfchen : : dissipative Vibrationsdynamik und Charakterisierung eines Nanoplasmas
Vibrational structure and dynamics of triatomic alkali molecules and RbHe exciplexes on helium nanodroplets investigated with femtosecond and picosecond pump-probe techniques : = Vibrationsstruktur und Dynamik von dreiatomigen Alkalimolekülen und RbHe Exziplexen auf Helium Nanotröpfchen, untersucht mit Femtosekunden und Picosekunden Pump-Probe Techniken
Spektroskopische Untersuchungen an Tetracen und PTCDA-Molekülen eingelagert in Helium-Nanotröpfchen oder auf der Oberfläche von Edelgasclustern Beeinflussung der Fluoreszenzlebensdauer durch kollektive Effekte
Solvation of atoms and molecules and their interactions with rare gas and hydrogen clusters : = Solvatisierung von Atomen und Molekülen und deren Wechselwirkung mit Edelgas- und Wasserstoff-Clustern
Diffraction imaging of light induced dynamics in xenon-doped helium nanodroplets
Spin-state-controlled chemi-ionization reactions between metastable helium atoms and ground-state lithium atoms
Influence of an atomic resonance on the coherent control of the photoionization process
Phase-modulated coherent time-domain spectroscopy in the extreme ultraviolet regime
Time-resolved photoelectron and photoion spectroscopy of atomic and molecular clusters using XUV radiation
Fluorescence lifetime reduction mechanisms of organic complexes studied by cluster isolation spectroscopy