Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

to related objects

Abstract: Tuning morphologies of self‐assembled structures in water is a major challenge. Herein we present a salen‐based amphiphile which, using complexation with distinct transition metal ions, allows to control effectively the self‐assembly morphology in water, as observed by Cryo‐TEM and confirmed by DLS measurements. Applying this strategy with various metal ions gives a broad spectrum of self‐assembled structures starting from the same amphiphilic ligand (from cubic structures to vesicles and micelles). Thermogravimetric analysis and electric conductivity measurements reveal a key role for water coordination apparently being responsible for the distinct assembly behavior.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation ; volume:58 ; number:42 ; year:2019 ; pages:14935-14939 ; extent:5
Angewandte Chemie / International edition. International edition ; 58, Heft 42 (2019), 14935-14939 (gesamt 5)

Creator: Tosi, Filippo
Stuart, Marc C. A.
Wezenberg, Sander J.
Feringa, Ben L.

DOI: 10.1002/anie.201908010

URN: urn:nbn:de:101:1-2022073011223665875216

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:38 AM CEST

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.

Show original at data provider

Associated

Tosi, Filippo
Stuart, Marc C. A.
Wezenberg, Sander J.
Feringa, Ben L.

Other Objects (12)

Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Stereodivergent Anion Binding Catalysis with Molecular Motors

Stereodivergent Anion Binding Catalysis with Molecular Motors

Photoresponsive Supramolecular Polymers: From Light‐Controlled Small Molecules to Smart Materials

Photoresponsive Supramolecular Polymers: From Light‐Controlled Small Molecules to Smart Materials

Stereodivergent Anion Binding Catalysis with Molecular Motors

Stereodivergent Anion Binding Catalysis with Molecular Motors

Introduction of Molecular Complexity via the Cross‐Coupling of Lithium 1,4‐Dioxene with Aryl Bromides

Introduction of Molecular Complexity via the Cross‐Coupling of Lithium 1,4‐Dioxene with Aryl Bromides

Direct Catalytic N ‐Alkylation of α‐Amino Acid Esters and Amides Using Alcohols with High Retention of Stereochemistry

Direct Catalytic N ‐Alkylation of α‐Amino Acid Esters and Amides Using Alcohols with High Retention of Stereochemistry

Regioselective Synthesis of Indanones

Regioselective Synthesis of Indanones

Synthetic Approaches to Highly Functional β-Carboline Building Blocks via Allylic Amidation

Synthetic Approaches to Highly Functional β-Carboline Building Blocks via Allylic Amidation

Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties

Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties

Highly Efficient Biobased Synthesis of Acrylic Acid

Highly Efficient Biobased Synthesis of Acrylic Acid

Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Stereodivergent Anion Binding Catalysis with Molecular Motors

Stereodivergent Anion Binding Catalysis with Molecular Motors

Photoresponsive Supramolecular Polymers: From Light‐Controlled Small Molecules to Smart Materials

Photoresponsive Supramolecular Polymers: From Light‐Controlled Small Molecules to Smart Materials

Stereodivergent Anion Binding Catalysis with Molecular Motors

Stereodivergent Anion Binding Catalysis with Molecular Motors

Introduction of Molecular Complexity via the Cross‐Coupling of Lithium 1,4‐Dioxene with Aryl Bromides

Introduction of Molecular Complexity via the Cross‐Coupling of Lithium 1,4‐Dioxene with Aryl Bromides

Direct Catalytic N ‐Alkylation of α‐Amino Acid Esters and Amides Using Alcohols with High Retention of Stereochemistry

Direct Catalytic N ‐Alkylation of α‐Amino Acid Esters and Amides Using Alcohols with High Retention of Stereochemistry

Regioselective Synthesis of Indanones

Regioselective Synthesis of Indanones

Synthetic Approaches to Highly Functional β-Carboline Building Blocks via Allylic Amidation

Synthetic Approaches to Highly Functional β-Carboline Building Blocks via Allylic Amidation

Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties

Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties

Highly Efficient Biobased Synthesis of Acrylic Acid

Highly Efficient Biobased Synthesis of Acrylic Acid

Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

Salen‐Based Amphiphiles: Directing Self‐Assembly in Water by Metal Complexation

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media

Stereodivergent Anion Binding Catalysis with Molecular Motors

Stereodivergent Anion Binding Catalysis with Molecular Motors

Photoresponsive Supramolecular Polymers: From Light‐Controlled Small Molecules to Smart Materials

Photoresponsive Supramolecular Polymers: From Light‐Controlled Small Molecules to Smart Materials

Stereodivergent Anion Binding Catalysis with Molecular Motors

Stereodivergent Anion Binding Catalysis with Molecular Motors

Introduction of Molecular Complexity via the Cross‐Coupling of Lithium 1,4‐Dioxene with Aryl Bromides

Introduction of Molecular Complexity via the Cross‐Coupling of Lithium 1,4‐Dioxene with Aryl Bromides

Direct Catalytic N ‐Alkylation of α‐Amino Acid Esters and Amides Using Alcohols with High Retention of Stereochemistry

Direct Catalytic N ‐Alkylation of α‐Amino Acid Esters and Amides Using Alcohols with High Retention of Stereochemistry

Regioselective Synthesis of Indanones

Regioselective Synthesis of Indanones

Synthetic Approaches to Highly Functional β-Carboline Building Blocks via Allylic Amidation

Synthetic Approaches to Highly Functional β-Carboline Building Blocks via Allylic Amidation

Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties

Synthesis of Styrylbenzazole Photoswitches and Evaluation of their Photochemical Properties

Highly Efficient Biobased Synthesis of Acrylic Acid

Highly Efficient Biobased Synthesis of Acrylic Acid

Cultural heritage institutions wishing to register will find more information here.

Fields marked * need to be filled in.

Username*

Please enter your username

Email*

Please enter your email address

Please do not fill this field

First name

Last name

Password*

Please enter your password

Confirm password*

Please enter the same password

I have read the terms of use and the privacy policy for the collection of personal data and accept them. *

This field is required.

I would like to subscribe to the newsletter of the Deutsche Digitale Bibliothek. See newsletter subscription info.

Account created

Your "My DDB" account has been successfully created. Before you can log in to your account, you must click the confirmation link in the message we just sent to the email address you provided.