Highly Efficient Biobased Synthesis of Acrylic Acid

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Abstract: Petrochemical based polymers, paints and coatings are cornerstones of modern industry but our future sustainable society demands greener processes and renewable feedstock materials. A challenge is to access platform monomers from biomass resources while integrating the principles of green chemistry in their chemical synthesis. We present a synthesis route starting from biomass‐derived furfural towards the commonly used monomers maleic anhydride and acrylic acid, implementing environmentally benign photooxygenation, aerobic oxidation and ethenolysis reactions. Maleic anhydride and acrylic acid, transformed into sodium acrylate, were isolated in yields of 85 % (2 steps) and 81 % (4 steps), respectively. With minimal waste and high atom efficiency, this biobased route provides a viable alternative to access key monomers.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Highly Efficient Biobased Synthesis of Acrylic Acid ; day:13 ; month:12 ; year:2021 ; extent:7
Angewandte Chemie ; (13.12.2021) (gesamt 7)

Creator: Hermens, Johannes G. H.
Jensma, Andries
Feringa, Ben L.

DOI: 10.1002/ange.202112618

URN: urn:nbn:de:101:1-2021121314142742604054

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:22 AM CEST

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Hermens, Johannes G. H.
Jensma, Andries
Feringa, Ben L.

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