Gold carbonyl cations and beyond: homoleptic gold(i) complexes with P4 and P4S3 and the half-sandwich cation [Au(C6H6)(CO)]+
Abstract: Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the perfluoroalkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+ salt proved to be an excellent ‘naked’ Au+-synthon yielding complex salts with [Au(η2-P4)2]+, [Au(η1-P4S3)2]+ and half-sandwich [Au(η2-C6H6)(CO)]+ cation
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Anmerkungen
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Chemical communications. - 60, 41 (2024) , 5403-5406, ISSN: 1364-548X
- Ereignis
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Veröffentlichung
- (wo)
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Freiburg
- (wer)
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Universität
- (wann)
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2024
- Urheber
- Beteiligte Personen und Organisationen
- DOI
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10.1039/d4cc01374c
- URN
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urn:nbn:de:bsz:25-freidok-2472903
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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25.03.2025, 13:43 MEZ
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Beteiligte
- Schmitt, Manuel
- Nestle, Sarah
- Radtke, Valentin
- Krossing, Ingo
- Institut für Anorganische und Analytische Chemie. Freiburg im Breisgau
- Universität
Entstanden
- 2024
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