Introducing the perfluorinated Cp* ligand into coordination chemistry
Abstract: The reaction of AgBF4 and [Rh(COD)Cl]2 (COD=1,5-cyclooctadiene) in presence of [NEt4][C5(CF3)5] afforded the fluorocarbon soluble complex [Rh(COD)(C5(CF3)5)] by salt metathesis. This complex represents the first example for a successful coordination of the weakly basic [C5(CF3)5]− ligand, since its first synthesis in 1980. In addition to [Rh(COD)(C5(CF3)5)] also the byproduct [Rh(COD)(C5(CF3)4H)] was isolated and fully characterized. Accompanying DFT studies showed that the interaction energy of the [C5(CF3)5]− ligand towards the 12-electron fragment [Rh(COD)]+ is ≈70 kcal mol−1 lower in comparison to [C5(CH3)5]− due to reduced electrostatic interactions and weaker π-donor properties of the ligand. The quantitative but reversible substitution of the [C5(CF3)5]− ligand by toluene, converting it into a weakly coordinating anion, experimentally proved the extraordinary weak bonding interaction
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Anmerkungen
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Angewandte Chemie. International edition. - 61, 43 (2022) , e202211147, ISSN: 1521-3773
- Ereignis
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Veröffentlichung
- (wo)
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Freiburg
- (wer)
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Universität
- (wann)
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2022
- Urheber
- DOI
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10.1002/anie.202211147
- URN
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urn:nbn:de:bsz:25-freidok-2314471
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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25.03.2025, 13:46 MEZ
Datenpartner
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Beteiligte
- Sievers, Robin
- Sellin, Malte
- Rupf, Susanne M.
- Parche, Joshua
- Malischewski, Moritz
- Universität
Entstanden
- 2022
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