Reconfigurable Materials Based on Photocontrolled Metal–Ligand Coordination
Photoresponsive materials have attracted growing interest because of their potential applications in materials science, such as photoswitches, photopatterning, information storage, and so on. However, there are some challenges for photoresponsive materials for certain applications: 1) Only a few photoresponsive surfaces are transformed into multiple states after photoreactions to adapt to changing environmental conditions; 2) Photoresponsive materials may not function properly in cold environments, especially for gels. To address these problems, we have recently developed photoresponsive materials based on ruthenium (Ru) complexes. Such Ru complexes showed a photoinduced ligand substitution under visible light irradiation. Reconfigurable surfaces that can adapt to environmental changes and photoresponsive organohydrogels that function effectively at sub‐zero temperatures have been fabricated using photoresponsive Ru complexes. Herein, it is demonstrated that based on photocontrolled Ru–ligand coordination, reconfigurable surfaces can be modified for user‐defined functions via visible light irradiation and that photoresponsive gels can function even at –20 °C. As a perspective, Ru‐containing photoresponsive complexes could open up pathways for a variety of applications.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Reconfigurable Materials Based on Photocontrolled Metal–Ligand Coordination ; volume:2 ; number:10 ; year:2020 ; extent:6
Advanced intelligent systems ; 2, Heft 10 (2020) (gesamt 6)
- Creator
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Han, Jianxiong
Huang, Yun-shuai
Yang, Ni
Wu, Si
- DOI
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10.1002/aisy.202000112
- URN
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urn:nbn:de:101:1-2022062911043710541827
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:31 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Han, Jianxiong
- Huang, Yun-shuai
- Yang, Ni
- Wu, Si
Other Objects (12)
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Metal- and Ligand-Centered Chirality in Square-Planar Coordination Compounds
A Tris(terpyridine) Ligand-based Metal Coordination Nanosheet as Electrode Material with Good Supercapacitor Performance
Metal–ligand Lability and Ligand Mobility Enables Framework Transformation via Ligand Release in a Family of Crystalline 2D Coordination Polymers
Synthesis and Characterization of Polydentate C3 Symmetric Ligand Systems in Metal Coordination
Self-assembly of Bay-substituted perylene bisimide by ligand-metal ion coordination
Alternating Metal‐Ligand Coordination Improves Electrocatalytic CO 2 Reduction by a Mononuclear Ru Catalyst **
Alternating Metal‐Ligand Coordination Improves Electrocatalytic CO 2 Reduction by a Mononuclear Ru Catalyst **
Introducing the Bis (mesitoyl) phosphide Ligand into Dinuclear Trivalent Rare Earth Metal Coordination Chemistry
Toughening self-healing elastomer crosslinked by metal–ligand coordination through mixed counter anion dynamics
Immunoregulation of macrophages by dynamic ligand presentation via ligand–cation coordination
Harnessing Coordination‐Assisted Surface Functionalization for Ligand‐Induced Growth of Ultrafine Metal Nanoparticles on MXene
Reconfiguring surface functions using visible-light-controlled metal-ligand coordination
Metal- and Ligand-Centered Chirality in Square-Planar Coordination Compounds
A Tris(terpyridine) Ligand-based Metal Coordination Nanosheet as Electrode Material with Good Supercapacitor Performance
Metal–ligand Lability and Ligand Mobility Enables Framework Transformation via Ligand Release in a Family of Crystalline 2D Coordination Polymers
Synthesis and Characterization of Polydentate C3 Symmetric Ligand Systems in Metal Coordination
Self-assembly of Bay-substituted perylene bisimide by ligand-metal ion coordination
Alternating Metal‐Ligand Coordination Improves Electrocatalytic CO 2 Reduction by a Mononuclear Ru Catalyst **
Alternating Metal‐Ligand Coordination Improves Electrocatalytic CO 2 Reduction by a Mononuclear Ru Catalyst **
Introducing the Bis (mesitoyl) phosphide Ligand into Dinuclear Trivalent Rare Earth Metal Coordination Chemistry
Toughening self-healing elastomer crosslinked by metal–ligand coordination through mixed counter anion dynamics
Immunoregulation of macrophages by dynamic ligand presentation via ligand–cation coordination