Reaction mechanisms of high‐rate copper electrochemical machining in nitrate electrolytes

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Abstract: The high-rate electrochemical dissolution of copper in nitrate electrolytes is investigated primarily via polarization curves, while varying parameters such as the electrolyte flow velocity, the electrolyte resistance, the anode geometry, and the temperature. This study focuses on the re-rise in current at high voltages after the limiting current plateau. As a result of the studies, a change in the complexation mechanism from hydration to “solvo-nitration” is proposed, which requires an additional potential drop within the electrochemical double layer

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Notes: Angewandte Chemie. - 63, 45 (2024) , e202412876, ISSN: 1521-3773

Event: Veröffentlichung

(where): Freiburg

(who): Universität

(when): 2025

Creator: Jakob, Leonie
Bartsch, Jonas
Krossing, Ingo

Contributor: Albert-Ludwigs-Universität Freiburg. Freiburger Zentrum für interaktive Werkstoffe und bioinspirierte Technologien
Institut für Anorganische und Analytische Chemie. Freiburg im Breisgau
Freiburger Material-Forschungszentrum

DOI: 10.1002/anie.202412876

URN: urn:nbn:de:bsz:25-freidok-2620666

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:22 AM CEST

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2025

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Reaction mechanisms of high‐rate copper electrochemical machining in nitrate electrolytes

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Other Objects (12)

Reaction Mechanisms of High‐Rate Copper Electrochemical Machining in Nitrate Electrolytes

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