A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer
Abstract: Ethylene glycol has a transiently chiral, asymmetric global minimum structure, but it favors a highly symmetric, achiral dimer arrangement which has not been considered or found in previous quantum‐chemical studies. Complementary FTIR and Raman spectroscopy in supersonic jets allows for the detection and straightforward assignment of this four‐fold hydrogen‐bonded dimer, which introduces an interesting supramolecular binding motif for vicinal diols and provides a strong case for transient chirality synchronization.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer ; volume:55 ; number:14 ; year:2016 ; pages:4591-4595 ; extent:5
Angewandte Chemie / International edition. International edition ; 55, Heft 14 (2016), 4591-4595 (gesamt 5)
- Urheber
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Kollipost, Franz
Otto, Katharina E.
Suhm, Martin A.
- DOI
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10.1002/anie.201600603
- URN
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urn:nbn:de:101:1-2022103108063991314855
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:22 MESZ
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Beteiligte
- Kollipost, Franz
- Otto, Katharina E.
- Suhm, Martin A.
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