A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer
Abstract: Ethylene glycol has a transiently chiral, asymmetric global minimum structure, but it favors a highly symmetric, achiral dimer arrangement which has not been considered or found in previous quantum‐chemical studies. Complementary FTIR and Raman spectroscopy in supersonic jets allows for the detection and straightforward assignment of this four‐fold hydrogen‐bonded dimer, which introduces an interesting supramolecular binding motif for vicinal diols and provides a strong case for transient chirality synchronization.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer ; volume:128 ; number:14 ; year:2016 ; pages:4667-4671 ; extent:5
Angewandte Chemie ; 128, Heft 14 (2016), 4667-4671 (gesamt 5)
- Creator
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Kollipost, Franz
Otto, Katharina E.
Suhm, Martin A.
- DOI
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10.1002/ange.201600603
- URN
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urn:nbn:de:101:1-2022103104430315424697
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:30 AM CEST
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Associated
- Kollipost, Franz
- Otto, Katharina E.
- Suhm, Martin A.
Other Objects (12)
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Stereoselective synthesis of vicinal diols with enzymatic cascade reactions
Stereoselective synthesis of vicinal diols with enzymatic cascade reactions
Thermodynamic Control Enables trans-Selective Isomerization of Vicinal Diols via Iridium Photocatalysis
Oxidative Cleavage of Vicinal Diols Catalyzed by Monomeric Fe‐Sites Inside MFI Zeolite
An Eco‐Friendly and Switchable Carbon‐Based Catalyst for Protection‐Deprotection of Vicinal Diols
Studies directed toward the exploitation of vicinal diols in the synthesis of (+)-nebivolol intermediates
Enzymatic Asymmetric Synthesis of All Stereoisomers of Aliphatic, Vicinal Diols in Conventional and Non‐Conventional Media
Oxidation of Vicinal Diols to α‐Hydroxy Ketones with H 2 O 2 and a Simple Manganese Catalyst
tert-Butyl Ethers of Renewable Diols as Oxygenated Additives for Motor Gasoline. Part I: Glycerol and Propylene Glycol Ethers
Ethyl glycol, ethyl glycol acetate
Dimer
A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer
Stereoselective synthesis of vicinal diols with enzymatic cascade reactions
Stereoselective synthesis of vicinal diols with enzymatic cascade reactions
Thermodynamic Control Enables trans-Selective Isomerization of Vicinal Diols via Iridium Photocatalysis
Oxidative Cleavage of Vicinal Diols Catalyzed by Monomeric Fe‐Sites Inside MFI Zeolite
An Eco‐Friendly and Switchable Carbon‐Based Catalyst for Protection‐Deprotection of Vicinal Diols
Studies directed toward the exploitation of vicinal diols in the synthesis of (+)-nebivolol intermediates
Enzymatic Asymmetric Synthesis of All Stereoisomers of Aliphatic, Vicinal Diols in Conventional and Non‐Conventional Media
Oxidation of Vicinal Diols to α‐Hydroxy Ketones with H 2 O 2 and a Simple Manganese Catalyst
tert-Butyl Ethers of Renewable Diols as Oxygenated Additives for Motor Gasoline. Part I: Glycerol and Propylene Glycol Ethers
Ethyl glycol, ethyl glycol acetate