Non‐activated Esters as Reactive Handles in Direct Post‐Polymerization Modification
Abstract: Non‐activated esters are prominently featured functional groups in polymer science, as ester functional monomers display great structural diversity and excellent compatibility with a wide range of polymerization mechanisms. Yet, their direct use as a reactive handle in post‐polymerization modification has been typically avoided due to their low reactivity, which impairs the quantitative conversion typically desired in post‐polymerization modification reactions. While activated ester approaches are a well‐established alternative, the modification of non‐activated esters remains a synthetic and economically valuable opportunity. In this review, we discuss past and recent efforts in the utilization of non‐activated ester groups as a reactive handle to facilitate transesterification and aminolysis/amidation reactions, and the potential of the developed methodologies in the context of macromolecular engineering.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Non‐activated Esters as Reactive Handles in Direct Post‐Polymerization Modification ; day:02 ; month:07 ; year:2023 ; extent:17
Angewandte Chemie ; (02.07.2023) (gesamt 17)
- Urheber
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Van Guyse, Joachim F. R.
Bernhard, Yann
Podevyn, Annelore
Hoogenboom, Richard
- DOI
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10.1002/ange.202303841
- URN
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urn:nbn:de:101:1-2023070315121788545507
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 10:49 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Van Guyse, Joachim F. R.
- Bernhard, Yann
- Podevyn, Annelore
- Hoogenboom, Richard
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