Non‐activated Esters as Reactive Handles in Direct Post‐Polymerization Modification
Abstract: Non‐activated esters are prominently featured functional groups in polymer science, as ester functional monomers display great structural diversity and excellent compatibility with a wide range of polymerization mechanisms. Yet, their direct use as a reactive handle in post‐polymerization modification has been typically avoided due to their low reactivity, which impairs the quantitative conversion typically desired in post‐polymerization modification reactions. While activated ester approaches are a well‐established alternative, the modification of non‐activated esters remains a synthetic and economically valuable opportunity. In this review, we discuss past and recent efforts in the utilization of non‐activated ester groups as a reactive handle to facilitate transesterification and aminolysis/amidation reactions, and the potential of the developed methodologies in the context of macromolecular engineering.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Non‐activated Esters as Reactive Handles in Direct Post‐Polymerization Modification ; day:03 ; month:07 ; year:2023 ; extent:17
Angewandte Chemie / International edition. International edition ; (03.07.2023) (gesamt 17)
- Creator
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Van Guyse, Joachim F. R.
Bernhard, Yann
Podevyn, Annelore
Hoogenboom, Richard
- DOI
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10.1002/anie.202303841
- URN
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urn:nbn:de:101:1-2023070315243365302535
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:54 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Van Guyse, Joachim F. R.
- Bernhard, Yann
- Podevyn, Annelore
- Hoogenboom, Richard
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Functional polymers via post-polymerization modification of reactive polymers derived from 1,1- disubstituted-2-vinylcyclopropane
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Polymerization and reactive coating in supercritical carbon dioxide
Functional Polymers by Post-Polymerization Modification and Electrochemistry
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Modification of methylaluminoxane-activated ansa-zirconocene catalysts with triisobutylaluminum-transformations of reactive cations studied by NMR spectroscopy
Development of a Reactive Simulation Concept for Twin Polymerization
Two‐Photon Polymerization: Fundamentals, Materials, and Chemical Modification Strategies
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Polymerization of reactive S-vinyl monomers
Living anionic polymerization of activated aziridines
Functional polymers via post-polymerization modification of reactive polymers derived from 1,1- disubstituted-2-vinylcyclopropane
Actin polymerization is activated by terahertz irradiation
Functional Polymethylenes : Synthesis and Post-Polymerization Modification
Polymerization and reactive coating in supercritical carbon dioxide
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Modification of methylaluminoxane-activated ansa-zirconocene catalysts with triisobutylaluminum-transformations of reactive cations studied by NMR spectroscopy
Development of a Reactive Simulation Concept for Twin Polymerization