Methoxide‐Enabled Zirconium‐Catalyzed Migratory Alkene Hydrosilylation
Abstract: A zirconocene dichloride‐catalyzed alkene hydrosilylation is reported that can be applied to non‐activated and conjugated terminal and internal alkenes. It involves a catalytic Zr‐walk process and leads to a selective conversion to the linear product. Lithium methoxide serves as mild catalyst activating agent, which significantly increases the applicability and operational simplicity in comparison to earlier zirconium (II)‐based protocols. Supported by additional experiments and calculations, a mechanism via zirconium (IV) intermediates is proposed. Due to the benign nature and ready‐availability of the zirconium catalyst, the reaction is an attractive alternative to established alkene hydrosilylation methods.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Methoxide‐Enabled Zirconium‐Catalyzed Migratory Alkene Hydrosilylation ; volume:136 ; number:46 ; year:2024 ; extent:6
Angewandte Chemie ; 136, Heft 46 (2024) (gesamt 6)
- Creator
- DOI
-
10.1002/ange.202413182
- URN
-
urn:nbn:de:101:1-2411051309059.244897729081
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:28 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Luongo, Orsola A.
- Lemmerer, Miran
- Albers, Sanne L.
- Streuff, Jan
Other Objects (12)
Methoxide‐Enabled Zirconium‐Catalyzed Migratory Alkene Hydrosilylation
Cobalt‐Catalysed, Ligand‐Controlled Regiodivergent Alkene Hydrosilylation
Anomeric Amide‐Enabled Alkene‐Arene and Alkene‐Alkene Aminative Coupling
Heavier N-Heterocyclic Tetrylenes in Platinum-Catalyzed Alkene Hydrosilylation
Energy-transfer-enabled alkene isomerisation
Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
Zirconium (IV)‐Catalyzed Hydrosilylation of Organic Carbonates and Polycarbonates Household Wastes into Alcohol Derivatives () **
Transfer hydrosilylation
Hypervalent iodine-catalyzed amide and alkene coupling enabled by lithium salt activation
Enantioselective photocatalysis : alkene deracemization and [2π+2σ] photocycloadditions enabled by triplet energy transfer
Methoxide‐Enabled Zirconium‐Catalyzed Migratory Alkene Hydrosilylation
Cobalt‐Catalysed, Ligand‐Controlled Regiodivergent Alkene Hydrosilylation
Anomeric Amide‐Enabled Alkene‐Arene and Alkene‐Alkene Aminative Coupling
Heavier N-Heterocyclic Tetrylenes in Platinum-Catalyzed Alkene Hydrosilylation
Energy-transfer-enabled alkene isomerisation
Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
Zirconium (IV)‐Catalyzed Hydrosilylation of Organic Carbonates and Polycarbonates Household Wastes into Alcohol Derivatives () **
Transfer hydrosilylation
Hypervalent iodine-catalyzed amide and alkene coupling enabled by lithium salt activation
Enantioselective photocatalysis : alkene deracemization and [2π+2σ] photocycloadditions enabled by triplet energy transfer
Methoxide‐Enabled Zirconium‐Catalyzed Migratory Alkene Hydrosilylation
Cobalt‐Catalysed, Ligand‐Controlled Regiodivergent Alkene Hydrosilylation
Anomeric Amide‐Enabled Alkene‐Arene and Alkene‐Alkene Aminative Coupling
Heavier N-Heterocyclic Tetrylenes in Platinum-Catalyzed Alkene Hydrosilylation
Energy-transfer-enabled alkene isomerisation
Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
Zirconium (IV)‐Catalyzed Hydrosilylation of Organic Carbonates and Polycarbonates Household Wastes into Alcohol Derivatives () **
Transfer hydrosilylation
Hypervalent iodine-catalyzed amide and alkene coupling enabled by lithium salt activation