Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core–Shell Cobalt Nanoparticles
Abstract: Core–shell nanocatalysts are attractive due to their versatility and stability. Here, we describe cobalt nanoparticles encapsulated within graphitic shells prepared via the pyrolysis of a cationic poly‐ionic liquid (PIL) with a cobalt (II) chloride anion. The resulting material has a core–shell structure that displays excellent activity and selectivity in the self‐dehydrogenation and hetero‐dehydrogenation of primary amines to their corresponding imines. Furthermore, the catalyst exhibits excellent activity in the synthesis of secondary imines from substrates with various reducible functional groups (C=C, C≡C and C≡N) and amino acid derivatives.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core–Shell Cobalt Nanoparticles ; volume:132 ; number:19 ; year:2020 ; pages:7571-7577 ; extent:7
Angewandte Chemie ; 132, Heft 19 (2020), 7571-7577 (gesamt 7)
- Creator
- DOI
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10.1002/ange.201915526
- URN
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urn:nbn:de:101:1-2022052713434374802138
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Cui, Xinjiang
- Li, Wu
- Junge, Kathrin
- Fei, Zhaofu
- Beller, Matthias
- Dyson, Paul
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Entwicklung und Anwendung neuer Methoden zur Synthese von Antitumormitteln und antiviraler Wirkstoffe
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Iron- and manganese-catalysed (de)hydrogenation reactions
Base metal-catalyzed dehydrogenation of formic acid and alcohols
Late-Stage C–H Deuteration of Organic Compounds via Ligand-Enabled Palladium-Catalyzed Hydrogen Isotope Exchange
Sustainable synthesis of amines using molecularly defined and nanoparticles-based catalysts
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Cobalt‐Catalyzed Aqueous Dehydrogenation of Formic Acid
Iron catalysis : fundamentals and applications
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Entwicklung und Anwendung neuer Methoden zur Synthese von Antitumormitteln und antiviraler Wirkstoffe
Formic Acid Dehydrogenation by a Cyclometalated κ 3 ‐CNN Ruthenium Complex
Iron- and manganese-catalysed (de)hydrogenation reactions
Base metal-catalyzed dehydrogenation of formic acid and alcohols
Late-Stage C–H Deuteration of Organic Compounds via Ligand-Enabled Palladium-Catalyzed Hydrogen Isotope Exchange
Sustainable synthesis of amines using molecularly defined and nanoparticles-based catalysts
Hydrogen generation from the chemical energy carrier methanol : mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst system
A Selective and General Cobalt‐Catalyzed Hydroaminomethylation of Olefins to Amines
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