Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core–Shell Cobalt Nanoparticles
Abstract: Core–shell nanocatalysts are attractive due to their versatility and stability. Here, we describe cobalt nanoparticles encapsulated within graphitic shells prepared via the pyrolysis of a cationic poly‐ionic liquid (PIL) with a cobalt (II) chloride anion. The resulting material has a core–shell structure that displays excellent activity and selectivity in the self‐dehydrogenation and hetero‐dehydrogenation of primary amines to their corresponding imines. Furthermore, the catalyst exhibits excellent activity in the synthesis of secondary imines from substrates with various reducible functional groups (C=C, C≡C and C≡N) and amino acid derivatives.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core–Shell Cobalt Nanoparticles ; volume:132 ; number:19 ; year:2020 ; pages:7571-7577 ; extent:7
Angewandte Chemie ; 132, Heft 19 (2020), 7571-7577 (gesamt 7)
- Urheber
- DOI
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10.1002/ange.201915526
- URN
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urn:nbn:de:101:1-2022052713434374802138
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:23 MESZ
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Beteiligte
- Cui, Xinjiang
- Li, Wu
- Junge, Kathrin
- Fei, Zhaofu
- Beller, Matthias
- Dyson, Paul
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