Phenothiazine‐functionalized poly(norbornene)s as high‐rate cathode‐materials for organic batteries
Abstract: Organic cathode materials are handled as promising candidates for new energy‐storage solutions based on their transition‐metal‐free composition. Phenothiazine‐based polymers are attractive owing to their redox potential of 3.5 V vs. Li/Li+ and high cycling stabilities. Herein, three types of poly(norbornene)s were investigated, functionalized with phenothiazine units through either a direct connection or ester linkages, as well as their crosslinked derivatives. The directly linked poly(3‐norbornylphenothiazine)s demonstrated excellent rate capability and cycling stability with a capacity retention of 73 % after 10 000 cycles at a C‐rate of 100 C for the crosslinked polymer. The polymer network structure of the crosslinked poly(3‐norbornylphenothiazine) was beneficial for its rate performance
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Notes
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ChemSusChem. - 13, 9 (2020) , 2232-2238, ISSN: 1864-564X
- Keyword
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Phenothiazin
- Event
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Veröffentlichung
- (where)
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Freiburg
- (who)
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Universität
- (when)
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2020
- DOI
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10.1002/cssc.201903168
- URN
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urn:nbn:de:bsz:25-freidok-1519877
- Rights
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Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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25.03.2025, 1:43 PM CET
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
Time of origin
- 2020
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