Design, fabrication and prototype testing of a chip integrated micro PEM fuel cell accumulator combined on-board range extender

Abstract: In this work we present the design, fabrication and prototype testing of Chip Integrated Micro PEM Fuel Cell Accumulator (CIμ-PFCA) combined On-Board Range Extender (O-BRE). CIμ-PFCA is silicon based micro-PEM fuel cell system with an integrated hydrogen storage feature (palladium metal hydride), the run time of CIμ-PFCA is dependent on the stored hydrogen, and in order to extend its run time an O-BRE is realized (catalytic hydrolysis of chemical hydride, NaBH4. Combining the CIμ-PFCA and O-BRE on a system level have few important design requirements to be considered; hydrogen regulation, gas -liquid separator between the CIμ-PFCA and the O-RE. The usage of traditional techniques to regulate hydrogen (tubes), gas-liquid phase membranes (porous membrane separators) are less desirable in the micro domain, due to its space constraint. Our approach is to use a passive hydrogen regulation and gas-liquid phase separation concept; to use palladium membrane. Palladium regulates hydrogen by concentration diffusion, and its property to selectively adsorb only hydrogen is used as a passive gas-liquid phase separator. Proof of concept is shown by realizing a prototype system. The system is an assembly of CIμ-PFCA, palladium membrane and the O-BRE. The CIμ-PFCA consist of 2 individually processed silicon chips, copper supported palladium membrane realized by electroplating followed by high temperature annealing process under inter atmosphere and the O-BRE is realized out of a polymer substrate by micromilling process with platinum coated structures, which functions as a catalyst for the hydrolysis of NaBH4. The functionality of the assembled prototype system is demonstrated by the measuring a unit cell (area 1 mm2) when driven by the catalytic hydrolysis of chemical hydride (NaBH4 and the prototype system shows run time more than 15 hours

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch
Anmerkungen
Journal of physics. Conference Series. - 557 (2014) , 012049, ISSN: 1742-6596

Klassifikation
Elektrotechnik, Elektronik

Ereignis
Veröffentlichung
(wo)
Freiburg
(wer)
Universität
(wann)
2019
Urheber
Balakrishnan, Arvind
Müller, Claas
Reinecke, Holger
Beteiligte Personen und Organisationen

DOI
10.1088/1742-6596/557/1/012049
URN
urn:nbn:de:bsz:25-freidok-1208609
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
25.03.2025, 13:42 MEZ

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Beteiligte

Entstanden

  • 2019

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