Unlocking Photocatalytic Activity of Acridinium Salts by Anion‐Binding Co‐Catalysis
Abstract: The in situ generation of active photoredox organic catalysts upon anion‐binding co‐catalysis by making use of the ionic nature of common photosensitizers is reported. Hence, the merge of anion‐binding and photocatalysis permitted the modulation of the photocatalytic activity of simple acridinium halide salts, building an effective anion‐binding – photoredox ion pair complex able to promote a variety of visible light driven transformations, such as anti‐Markovnikov addition to olefins, Diels‐Alder and the desilylative C−C bond forming reactions. Anion‐binding studies, together with steady‐state and time‐resolved spectroscopy analysis, supported the postulated ion pair formation between the thiourea hydrogen‐bond donor organocatalyst and the acridinium salt, which proved essential for unlocking the photocatalytic activity of the photosensitizer.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Unlocking Photocatalytic Activity of Acridinium Salts by Anion‐Binding Co‐Catalysis ; day:19 ; month:06 ; year:2024 ; extent:9
Chemistry - a European journal ; (19.06.2024) (gesamt 9)
- Creator
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Pérez‐Aguilar, María C.
Entgelmeier, Lukas‐M.
Herrera‐Luna, Jorge C.
Daniliuc, Constantin Gabriel
Consuelo Jiménez, M.
Pérez‐Ruiz, Raúl
García Mancheño, Olga
- DOI
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10.1002/chem.202400541
- URN
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urn:nbn:de:101:1-2406191452040.726340653570
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:52 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Pérez‐Aguilar, María C.
- Entgelmeier, Lukas‐M.
- Herrera‐Luna, Jorge C.
- Daniliuc, Constantin Gabriel
- Consuelo Jiménez, M.
- Pérez‐Ruiz, Raúl
- García Mancheño, Olga
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Stereodivergent Anion Binding Catalysis with Molecular Motors
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Anion‐ π Catalysis: Focus on Nonadjacent Stereocenters
Anion–π Catalysis Enabled by the Mechanical Bond **
Anion–π Catalysis Enabled by the Mechanical Bond **
Enantioselective Nucleophilic Dearomatization of Heteroarenes by Anion-Binding-Catalysis
Anion-binding catalysis
Thiourea Catalysis via Anion Binding
Unlocking Catalysis Using Oxidatively Induced Reductive Elimination
Anion–π catalysis on carbon allotropes
Unlocking New Reactivities in Enzymes by Iminium Catalysis
Unlocking New Reactivities in Enzymes by Iminium Catalysis
Stereodivergent Anion Binding Catalysis with Molecular Motors
Stereodivergent Anion Binding Catalysis with Molecular Motors
Anion‐ π Catalysis: Focus on Nonadjacent Stereocenters
Anion–π Catalysis Enabled by the Mechanical Bond **
Anion–π Catalysis Enabled by the Mechanical Bond **
Enantioselective Nucleophilic Dearomatization of Heteroarenes by Anion-Binding-Catalysis
Anion-binding catalysis
Thiourea Catalysis via Anion Binding
Unlocking Catalysis Using Oxidatively Induced Reductive Elimination
Anion–π catalysis on carbon allotropes
Unlocking New Reactivities in Enzymes by Iminium Catalysis
Unlocking New Reactivities in Enzymes by Iminium Catalysis
Stereodivergent Anion Binding Catalysis with Molecular Motors
Stereodivergent Anion Binding Catalysis with Molecular Motors
Anion‐ π Catalysis: Focus on Nonadjacent Stereocenters
Anion–π Catalysis Enabled by the Mechanical Bond **
Anion–π Catalysis Enabled by the Mechanical Bond **