Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
Abstract: Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional‐group tolerance and mild conditions of the method have allowed for the two‐step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids ; volume:129 ; number:9 ; year:2017 ; pages:2522-2526 ; extent:5
Angewandte Chemie ; 129, Heft 9 (2017), 2522-2526 (gesamt 5)
- Creator
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Ochiai, Hidenori
Uetake, Yuta
Niwa, Takashi
Hosoya, Takamitsu
- DOI
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10.1002/ange.201611974
- URN
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urn:nbn:de:101:1-2022091606420189280834
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:28 AM CEST
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Associated
- Ochiai, Hidenori
- Uetake, Yuta
- Niwa, Takashi
- Hosoya, Takamitsu
Other Objects (12)
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Rhodium-Catalyzed Enantioselective Desymmetrization
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Photocatalytic direct borylation of carboxylic acids
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Radical C−N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent
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Rhodium-Catalyzed Enantioselective Hydroacylation of Ketones
Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
Regioselective Aromatic C–H Borylation
Rhodacycles Activity in P‐Directed Rhodium‐Catalyzed Synthesis of π‐Extended Aromatic Fluoranthenyl Phosphines
Rhodium-Catalyzed Enantioselective Desymmetrization
Rhodium-Catalyzed Macrocyclization of Peptides
Rhodium-Catalyzed Asymmetric Transfer Hydrogenation
Photocatalytic direct borylation of carboxylic acids
Hydrogen Bond Directed ortho ‐Selective C−H Borylation of Secondary Aromatic Amides
Radical C−N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent
Hydrogen Bond Directed ortho ‐Selective C−H Borylation of Secondary Aromatic Amides
Rhodium-Catalyzed Asymmetric Arylation of Diarylmethylamines
Rhodium-Catalyzed Enantioselective Hydroacylation of Ketones
Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
Regioselective Aromatic C–H Borylation
Rhodacycles Activity in P‐Directed Rhodium‐Catalyzed Synthesis of π‐Extended Aromatic Fluoranthenyl Phosphines
Rhodium-Catalyzed Enantioselective Desymmetrization
Rhodium-Catalyzed Macrocyclization of Peptides
Rhodium-Catalyzed Asymmetric Transfer Hydrogenation
Photocatalytic direct borylation of carboxylic acids
Hydrogen Bond Directed ortho ‐Selective C−H Borylation of Secondary Aromatic Amides
Radical C−N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent
Hydrogen Bond Directed ortho ‐Selective C−H Borylation of Secondary Aromatic Amides
Rhodium-Catalyzed Asymmetric Arylation of Diarylmethylamines