Pd-Catalyzed Asymmetric Allylic Substitution Cascade via Desymmetrization for the Construction of Chiral Polyheterocycles
Abstract: Chiral polyheterocycles represent an important class of compounds because of their prevalence in bioactive natural products and chiral drugs. Pd-catalyzed allylic substitution is a powerful synthetic tool for forming C–C and C–X bonds (X = N, O, S, etc.). Naturally, asymmetric cascade reactions that utilize allylic substitution are undoubtedly efficient pathways to construct heterocycles. In this article, we reviewed the Pd-catalyzed asymmetric allylic substitution cascade via the desymmetrization of meso-diol diesters of cycloolefins, for the construction of chiral polyheterocycles and their derivatives.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Pd-Catalyzed Asymmetric Allylic Substitution Cascade via Desymmetrization for the Construction of Chiral Polyheterocycles ; volume:06 ; number:03 ; year:2024 ; pages:e237-e251
Pharmaceutical fronts ; 06, Heft 03 (2024), e237-e251
- Contributor
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Kou, Xuezhen
Xu, Yongjin
Dong, Siqi
Liu, Hui
Liu, Delong
Zhang, Wanbin
- DOI
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10.1055/s-0044-1788722
- URN
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urn:nbn:de:101:1-2411211000142.159818696081
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:39 AM CEST
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Associated
- Kou, Xuezhen
- Xu, Yongjin
- Dong, Siqi
- Liu, Hui
- Liu, Delong
- Zhang, Wanbin
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