Ring‐Expanded N‐Heterocyclic Carbenes for Copper‐Mediated Azide–Alkyne Click Cycloaddition Reactions

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Abstract: A series of well‐defined copper (I) complexes bearing ring‐expanded N‐heterocyclic carbene (NHC) ligands has been applied to the azide–alkyne cycloaddition reaction. The obtained results notably showed that the six‐membered NHC ligands outperform well‐established five‐membered ones. [CuI (Mes‐6)] displayed a remarkable catalytic activity while respecting the strict criteria for click reactions.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Ring‐Expanded N‐Heterocyclic Carbenes for Copper‐Mediated Azide–Alkyne Click Cycloaddition Reactions ; volume:10 ; number:9 ; year:2018 ; pages:2041-2045 ; extent:5
ChemCatChem ; 10, Heft 9 (2018), 2041-2045 (gesamt 5)

Creator: Sebest, Filip
Dunsford, Jay J.
Adams, Matthew
Pivot, Jeremy
Newman, Paul D.
Díez‐González, Silvia

DOI: 10.1002/cctc.201701992

URN: urn:nbn:de:101:1-2022081905505646997529

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:28 AM CEST

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Associated

Sebest, Filip
Dunsford, Jay J.
Adams, Matthew
Pivot, Jeremy
Newman, Paul D.
Díez‐González, Silvia

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Ring‐Expanded N‐Heterocyclic Carbenes for Copper‐Mediated Azide–Alkyne Click Cycloaddition Reactions

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Other Objects (12)

Copper-Catalyzed Alkyne–Azide Cycloaddition by Kinetic Resolution

Conditional Copper‐Catalyzed Azide–Alkyne Cycloaddition by Catalyst Encapsulation †

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Conjugating Hemoglobin and Albumin by Strain‐Promoted Azide‐ Alkyne Cycloaddition

Alkyne–Azide Cycloaddition on Water-Soluble Copper NP–Cobaltocene Catalyst

Azide–Alkyne Cycloaddition with a Melanin-Supported Copper(I) Catalyst

Selective DNA modification using the Cu(I)-catalyzed alkyne-azide cycloaddition

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Copper-Catalyzed Alkyne–Azide Cycloaddition by Kinetic Resolution

Conditional Copper‐Catalyzed Azide–Alkyne Cycloaddition by Catalyst Encapsulation †

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Conjugating Hemoglobin and Albumin by Strain‐Promoted Azide‐ Alkyne Cycloaddition

Alkyne–Azide Cycloaddition on Water-Soluble Copper NP–Cobaltocene Catalyst

Azide–Alkyne Cycloaddition with a Melanin-Supported Copper(I) Catalyst

Selective DNA modification using the Cu(I)-catalyzed alkyne-azide cycloaddition

Efficient catenane synthesis by cucurbit[6]uril-mediated azide–alkyne cycloaddition

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Copper-Catalyzed Alkyne–Azide Cycloaddition by Kinetic Resolution

Conditional Copper‐Catalyzed Azide–Alkyne Cycloaddition by Catalyst Encapsulation †

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