Influence of site-classification approach on geochemical background values

Abstract: This study of peri-urban minerogenic topsoil on glacigenic or post-glacial deposits shows the influence of the site-classification approach on the differentiated median background (DMB) values of major elements and the potentially harmful elements (PHEs) Ba, Cr, Cu, Mn, Ni, Pb and Zn. Composite samples from forests and meadows were taken in 25 sites, each of which had five sub-sites. A fraction of <2 mm was used to determine the organic matter by loss on ignition (LOI), grain size by laser diffraction and the elemental contents by X-ray fluorescence. The following five site-classification approaches are compared: geochemical (G), using relative median contents of Al, K, Ti; textural (T), according to mean percentages of clay-sized fraction (CLF) and silt fraction (SIF); lithological (L), based on soil parent material texture from the soil database; soil type (S), presented in the soil database; and parent material (P), generalising the underlying Quaternary deposits. Sites were classified into four level groups in which the DMB values were estimated after eliminating anomalies. The average ranks of three scores according to SIF, CLF, LOI, Al, K, Ti, Fe, Mg, Ca and S in the respective groups revealed the highest value for the G approach. It better eliminates the CLF and SIF influences on the median assessment indices of PHEs in sites.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Influence of site-classification approach on geochemical background values ; volume:18 ; number:1 ; year:2020 ; pages:1391-1411 ; extent:21
Open chemistry ; 18, Heft 1 (2020), 1391-1411 (gesamt 21)

Creator
Zinkutė, Rimantė
Taraškevičius, Ričardas
Jankauskaitė, Margarita
Kazakauskas, Vaidotas
Stankevičius, Žilvinas

DOI
10.1515/chem-2020-0177
URN
urn:nbn:de:101:1-2410161731371.056046023960
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:24 AM CEST

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Associated

  • Zinkutė, Rimantė
  • Taraškevičius, Ričardas
  • Jankauskaitė, Margarita
  • Kazakauskas, Vaidotas
  • Stankevičius, Žilvinas

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