Cyclopentadienylnickel Chelates with Secondary or Tertiary Phosphane Tethers Bearing Imidazol‐2‐ylidene Ligands
Treatment of cyclopentadienylnickel chloro or bromo chelates bearing either a tertiary 2‐(di‐tert‐butyl) phosphanylethyl or a secondary 2‐(2,4,6‐trimethylphenyl) phosphanylethyl tether with imidazolylidene (Arduengo carbene) ligands results in cationic or electroneutral carbene complexes with either a decoordinated or a chelated tether. The outcome depends on the nature of the carbene, the counter anion, and the reactant stoichiometry. The results are the basis of ongoing investigations directed towards a deprotonation of the chelated cationic complexes with a secondary phosphorus atom.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Cyclopentadienylnickel Chelates with Secondary or Tertiary Phosphane Tethers Bearing Imidazol‐2‐ylidene Ligands ; volume:2020 ; number:26 ; year:2020 ; pages:2545-2551 ; extent:7
European journal of inorganic chemistry ; 2020, Heft 26 (2020), 2545-2551 (gesamt 7)
- Urheber
- DOI
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10.1002/ejic.202000326
- URN
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urn:nbn:de:101:1-2022061807154337727623
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:24 MESZ
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Beteiligte
- Werner, Irina
- Kohser, Stefanie
- Butenschön, Holger
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