Cyclopentadienylnickel Chelates with Secondary or Tertiary Phosphane Tethers Bearing Imidazol‐2‐ylidene Ligands
Treatment of cyclopentadienylnickel chloro or bromo chelates bearing either a tertiary 2‐(di‐tert‐butyl) phosphanylethyl or a secondary 2‐(2,4,6‐trimethylphenyl) phosphanylethyl tether with imidazolylidene (Arduengo carbene) ligands results in cationic or electroneutral carbene complexes with either a decoordinated or a chelated tether. The outcome depends on the nature of the carbene, the counter anion, and the reactant stoichiometry. The results are the basis of ongoing investigations directed towards a deprotonation of the chelated cationic complexes with a secondary phosphorus atom.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Cyclopentadienylnickel Chelates with Secondary or Tertiary Phosphane Tethers Bearing Imidazol‐2‐ylidene Ligands ; volume:2020 ; number:26 ; year:2020 ; pages:2545-2551 ; extent:7
European journal of inorganic chemistry ; 2020, Heft 26 (2020), 2545-2551 (gesamt 7)
- Creator
- DOI
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10.1002/ejic.202000326
- URN
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urn:nbn:de:101:1-2022061807154337727623
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:24 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Werner, Irina
- Kohser, Stefanie
- Butenschön, Holger
Other Objects (12)
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Cyclopentadienyl nickel complexes bearing a pendant phosphane tether
Separation and recycling of phosphane ligands from homogeneously catalyzed processes
Separation and recycling of phosphane ligands from homogeneously catalyzed processes
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Nickel (II) Phosphane‐ and N ‐heterocyclic Carbene Complexes with Tridentate, Dianionic (S,N,O) 2 – Ligands
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Cyclopentadienylnickel Chelates with Secondary or Tertiary Phosphane Tethers Bearing Imidazol-2-ylidene Ligands
Half-sandwich nickel(II) complexes bearing 1,3-di(cycloalkyl)imidazol-2-ylidene ligands
Cyclopentadienyl nickel complexes bearing a pendant phosphane tether
Separation and recycling of phosphane ligands from homogeneously catalyzed processes
Separation and recycling of phosphane ligands from homogeneously catalyzed processes
Ruthenium Cumulenylidene Complexes Bearing Heteroscorpionate Ligands
Wasserlösliche Phosphane
Magnesium Complexes with Isomeric Pyrazol‐4‐ylidene and Imidazol‐2‐ylidene Ligands
Gitterdynamik von Imidazol
P-Chirogenic Monodentate Phosphine Ligands Bearing 2-Biphenyl Group
Nickel (II) Phosphane‐ and N ‐heterocyclic Carbene Complexes with Tridentate, Dianionic (S,N,O) 2 – Ligands
Chemie der Carbonyl-Imidazol-Molybdän(0)-Komplexe [Carbonyl-Imidazol-Molybdän-Komplexe]
Cyclopentadienylnickel Chelates with Secondary or Tertiary Phosphane Tethers Bearing Imidazol-2-ylidene Ligands
Half-sandwich nickel(II) complexes bearing 1,3-di(cycloalkyl)imidazol-2-ylidene ligands
Cyclopentadienyl nickel complexes bearing a pendant phosphane tether
Separation and recycling of phosphane ligands from homogeneously catalyzed processes
Separation and recycling of phosphane ligands from homogeneously catalyzed processes
Ruthenium Cumulenylidene Complexes Bearing Heteroscorpionate Ligands
Wasserlösliche Phosphane
Magnesium Complexes with Isomeric Pyrazol‐4‐ylidene and Imidazol‐2‐ylidene Ligands
Gitterdynamik von Imidazol
P-Chirogenic Monodentate Phosphine Ligands Bearing 2-Biphenyl Group
Nickel (II) Phosphane‐ and N ‐heterocyclic Carbene Complexes with Tridentate, Dianionic (S,N,O) 2 – Ligands