Oriented Two‐Dimensional Porous Organic Cage Crystals
Abstract: The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution‐processable molecular crystalline 2D membranes for molecular separations.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Oriented Two‐Dimensional Porous Organic Cage Crystals ; volume:56 ; number:32 ; year:2017 ; pages:9391-9395 ; extent:5
Angewandte Chemie / International edition. International edition ; 56, Heft 32 (2017), 9391-9395 (gesamt 5)
- Urheber
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Jiang, Shan
Song, Qilei
Massey, Alan
Chong, Samantha Y.
Chen, Linjiang
Sun, Shijing
Hasell, Tom
Raval, Rasmita
Sivaniah, Easan
Cheetham, Anthony K.
Cooper, Andrew I.
- DOI
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10.1002/anie.201704579
- URN
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urn:nbn:de:101:1-2022091708091464925563
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:19 MESZ
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Beteiligte
- Jiang, Shan
- Song, Qilei
- Massey, Alan
- Chong, Samantha Y.
- Chen, Linjiang
- Sun, Shijing
- Hasell, Tom
- Raval, Rasmita
- Sivaniah, Easan
- Cheetham, Anthony K.
- Cooper, Andrew I.
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