Oriented Two‐Dimensional Porous Organic Cage Crystals

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Abstract: The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution‐processable molecular crystalline 2D membranes for molecular separations.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Oriented Two‐Dimensional Porous Organic Cage Crystals ; volume:129 ; number:32 ; year:2017 ; pages:9519-9523 ; extent:5
Angewandte Chemie ; 129, Heft 32 (2017), 9519-9523 (gesamt 5)

Creator: Jiang, Shan
Song, Qilei
Massey, Alan
Chong, Samantha Y.
Chen, Linjiang
Sun, Shijing
Hasell, Tom
Raval, Rasmita
Sivaniah, Easan
Cheetham, Anthony K.
Cooper, Andrew I.

DOI: 10.1002/ange.201704579

URN: urn:nbn:de:101:1-2022091708023739500004

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:23 AM CEST

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Associated

Jiang, Shan
Song, Qilei
Massey, Alan
Chong, Samantha Y.
Chen, Linjiang
Sun, Shijing
Hasell, Tom
Raval, Rasmita
Sivaniah, Easan
Cheetham, Anthony K.
Cooper, Andrew I.

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