Mechanical C−C Bond Formation by Laser Driven Shock Wave
Abstract: Mechanically induced C−C bond formation was demonstrated by the laser driven shock wave generated in liquid normal alkanes at room temperature. Gas chromatography mass spectrometry analysis revealed the dehydrogenation condensation between two alkane molecules, for seven normal alkanes from pentane to undecane. Major products were identified to be linear and branched alkane molecules with double the number of carbons, and exactly coincided with the molecules predicted by supposing that a C−C bond was formed between two starting molecules. The production of the alkane molecules showed that the C−C bond formation occurred almost evenly at all the carbon positions. The dependence of the production on the laser pulse energy clearly indicated that the process was attributed to the shock wave. The C−C bond formation observed was not a conventional passive chemical reaction but an unprecedented active reaction.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Mechanical C−C Bond Formation by Laser Driven Shock Wave ; volume:21 ; number:18 ; year:2020 ; pages:2104-2111 ; extent:8
ChemPhysChem ; 21, Heft 18 (2020), 2104-2111 (gesamt 8)
- Creator
-
Ishikawa, Wakako
Sato, Shunichi
- DOI
-
10.1002/cphc.202000563
- URN
-
urn:nbn:de:101:1-2022061905171643335669
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:30 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Ishikawa, Wakako
- Sato, Shunichi
Other Objects (12)
Extracorporeal Shock Wave Therapy: Quantitative Assessments of Mechanical Responses upon Radial Extracorporeal Shock Wave Therapy (Adv. Sci. 3/2018)
C-C bond activation
Quantitative Assessments of Mechanical Responses upon Radial Extracorporeal Shock Wave Therapy
Shock wave reflection phenomena
Shock wave reflection phenomena
Biocatalytic Formation of C-C Bonds
E.S.W.T. - extracorporeal shock wave therapy
Development of N-heterocyclic carbene catalyzed C-C bond cleavage and C-C bond formation reactions
Extra Corporeal Shock Wave – A New Wave of Therapy
Visible light induced C-C bond formation
Radial shock wave treatment of tendinopathies
Julia‐Kocienski‐Like Connective C−C and C=C Bond‐Forming Reaction
Extracorporeal Shock Wave Therapy: Quantitative Assessments of Mechanical Responses upon Radial Extracorporeal Shock Wave Therapy (Adv. Sci. 3/2018)
C-C bond activation
Quantitative Assessments of Mechanical Responses upon Radial Extracorporeal Shock Wave Therapy
Shock wave reflection phenomena
Shock wave reflection phenomena
Biocatalytic Formation of C-C Bonds
E.S.W.T. - extracorporeal shock wave therapy
Development of N-heterocyclic carbene catalyzed C-C bond cleavage and C-C bond formation reactions
Extra Corporeal Shock Wave – A New Wave of Therapy
Visible light induced C-C bond formation
Radial shock wave treatment of tendinopathies
Julia‐Kocienski‐Like Connective C−C and C=C Bond‐Forming Reaction
Extracorporeal Shock Wave Therapy: Quantitative Assessments of Mechanical Responses upon Radial Extracorporeal Shock Wave Therapy (Adv. Sci. 3/2018)
C-C bond activation
Quantitative Assessments of Mechanical Responses upon Radial Extracorporeal Shock Wave Therapy
Shock wave reflection phenomena
Shock wave reflection phenomena
Biocatalytic Formation of C-C Bonds
E.S.W.T. - extracorporeal shock wave therapy
Development of N-heterocyclic carbene catalyzed C-C bond cleavage and C-C bond formation reactions
Extra Corporeal Shock Wave – A New Wave of Therapy
Visible light induced C-C bond formation
Radial shock wave treatment of tendinopathies