Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis
Abstract: The two‐electron reduced forms of perylene diimides (PDIs) are luminescent closed‐shell species whose photochemical properties seem underexplored. Our proof‐of‐concept study demonstrates that straightforward (single) excitation of PDI dianions with green photons provides an excited state that is similarly or more reducing than the much shorter‐lived excited states of PDI radical monoanions, which are typically accessible after biphotonic excitation with blue photons. Thermodynamically demanding photocatalytic reductive dehalogenations and reductive C−O bond cleavage reactions of lignin model compounds have been performed using sodium dithionite acts as a reductant, either in aqueous solution or in biphasic water–acetonitrile mixtures in the presence of a phase transfer reagent. Our work illustrates the concept of multi‐electron reduction of a photocatalyst by a sacrificial reagent prior to irradiation with low‐energy photons as a means of generating very reactive excited states.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis ; day:20 ; month:12 ; year:2021 ; extent:10
Angewandte Chemie ; (20.12.2021) (gesamt 10)
- Creator
- DOI
-
10.1002/ange.202110491
- URN
-
urn:nbn:de:101:1-2021122114043267255498
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:36 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Li, Han
- Wenger, Oliver S.
Other Objects (12)
Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis
Hyōdai jo jōgen hochū Mōgyū : = Shinkan jo
Cage escape governs photoredox reaction rates and quantum yields
Mortality forecasting: How far back should we look in time?
Hyōdai jo jōgen hochū Mōgyū : = Senchū Mōgyū
Analysis of the development of the wind power industry in China — from the perspective of the financial support
Recent Advances in Wearable Aqueous Metal‐Air Batteries: From Configuration Design to Materials Fabrication
Risk factors of recurrent bacterial vaginosis among women of reproductive age: A cross-sectional study
Engineering a cyanobacterium as the catalyst for the photosynthetic conversion of CO2 to 1,2-propanediol
Comparative studies of alignment, alignment-free and SVM based approaches for predicting the hosts of viruses based on viral sequences
Analysing premature cardiovascular disease mortality in the United States by obesity status and educational attainment
Highway access and human capital investments in the rural regions of the People's Republic of China
Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis
Hyōdai jo jōgen hochū Mōgyū : = Shinkan jo
Cage escape governs photoredox reaction rates and quantum yields
Mortality forecasting: How far back should we look in time?
Hyōdai jo jōgen hochū Mōgyū : = Senchū Mōgyū
Analysis of the development of the wind power industry in China — from the perspective of the financial support
Recent Advances in Wearable Aqueous Metal‐Air Batteries: From Configuration Design to Materials Fabrication
Risk factors of recurrent bacterial vaginosis among women of reproductive age: A cross-sectional study
Engineering a cyanobacterium as the catalyst for the photosynthetic conversion of CO2 to 1,2-propanediol
Comparative studies of alignment, alignment-free and SVM based approaches for predicting the hosts of viruses based on viral sequences
Analysing premature cardiovascular disease mortality in the United States by obesity status and educational attainment
Highway access and human capital investments in the rural regions of the People's Republic of China
Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis
Hyōdai jo jōgen hochū Mōgyū : = Shinkan jo
Cage escape governs photoredox reaction rates and quantum yields
Mortality forecasting: How far back should we look in time?
Hyōdai jo jōgen hochū Mōgyū : = Senchū Mōgyū
Analysis of the development of the wind power industry in China — from the perspective of the financial support
Recent Advances in Wearable Aqueous Metal‐Air Batteries: From Configuration Design to Materials Fabrication
Risk factors of recurrent bacterial vaginosis among women of reproductive age: A cross-sectional study
Engineering a cyanobacterium as the catalyst for the photosynthetic conversion of CO2 to 1,2-propanediol
Comparative studies of alignment, alignment-free and SVM based approaches for predicting the hosts of viruses based on viral sequences
Analysing premature cardiovascular disease mortality in the United States by obesity status and educational attainment