Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling
Abstract: We report the stoichiometric and catalytic reactivity of organobismuth (I) complexes with organic azides. Treatment of N,C,N‐pincer bismuthinidenes with organic azides (acyl, sulfonyl, and bulky aryl) results in monomeric iminobismuthanes which can be structurally characterized —including the formal Bi=N double bond— by multinuclear NMR spectroscopy and single‐crystal X‐ray diffraction. Building upon the stoichiometric reactivity of the monomeric iminobismuthanes, catalytic reduction of a broad range of organic azides is developed. DFT calculations of the catalytic reaction pathway support the redox nature of the overall process.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling ; day:16 ; month:11 ; year:2024 ; extent:8
Angewandte Chemie ; (16.11.2024) (gesamt 8)
- Urheber
- DOI
-
10.1002/ange.202417864
- URN
-
urn:nbn:de:101:1-2411171338016.330443424219
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:31 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Won Moon, Hye
- Nöthling, Nils
- Leutzsch, Markus
- Kuziola, Jennifer
- Cornella, Josep
Ähnliche Objekte (12)
Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling
Bi, bi, bi, Bastion
Bi - bi - bi - Basjahn,
Electrochemical redox-cycling devices
Catalytic bi-reforming of methane for carbon dioxide ennoblement
HiCo-BiPEC. High Conductivity BiPolar-Electroce-Component : Hochleitfähige, graphitbasierte Bipolarelektrodeneinheit für Redox-Flow Batterien.
Recent advances in catalytic Wittig-type reactions based on P (III)/P (V) redox cycling
Construction and reactivity of Pt-based Bi-component catalytic systems
Bi
Bi
Bi
Bi
Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling
Bi, bi, bi, Bastion
Bi - bi - bi - Basjahn,
Electrochemical redox-cycling devices
Catalytic bi-reforming of methane for carbon dioxide ennoblement
HiCo-BiPEC. High Conductivity BiPolar-Electroce-Component : Hochleitfähige, graphitbasierte Bipolarelektrodeneinheit für Redox-Flow Batterien.
Recent advances in catalytic Wittig-type reactions based on P (III)/P (V) redox cycling
Construction and reactivity of Pt-based Bi-component catalytic systems
Bi
Bi
Bi
Bi
Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling
Bi, bi, bi, Bastion
Bi - bi - bi - Basjahn,
Electrochemical redox-cycling devices
Catalytic bi-reforming of methane for carbon dioxide ennoblement
HiCo-BiPEC. High Conductivity BiPolar-Electroce-Component : Hochleitfähige, graphitbasierte Bipolarelektrodeneinheit für Redox-Flow Batterien.
Recent advances in catalytic Wittig-type reactions based on P (III)/P (V) redox cycling
Construction and reactivity of Pt-based Bi-component catalytic systems
Bi
Bi
Bi