Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling
Abstract: We report the stoichiometric and catalytic reactivity of organobismuth (I) complexes with organic azides. Treatment of N,C,N‐pincer bismuthinidenes with organic azides (acyl, sulfonyl, and bulky aryl) results in monomeric iminobismuthanes which can be structurally characterized —including the formal Bi=N double bond— by multinuclear NMR spectroscopy and single‐crystal X‐ray diffraction. Building upon the stoichiometric reactivity of the monomeric iminobismuthanes, catalytic reduction of a broad range of organic azides is developed. DFT calculations of the catalytic reaction pathway support the redox nature of the overall process.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi (I)/Bi (III) Redox Cycling ; day:16 ; month:11 ; year:2024 ; extent:8
Angewandte Chemie ; (16.11.2024) (gesamt 8)
- Creator
- DOI
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10.1002/ange.202417864
- URN
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urn:nbn:de:101:1-2411171338016.330443424219
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:31 AM CEST
Data provider
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Won Moon, Hye
- Nöthling, Nils
- Leutzsch, Markus
- Kuziola, Jennifer
- Cornella, Josep
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