Reversible Postsynthetic Modification in a Metal–Organic Framework

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Abstract: Postsynthetic modification (PSM) of metal–organic frameworks (MOFs) provides access to functional materials and advanced porous solid engineering. Herein, we report the reversible PSM of a multivariate isoreticular MOF by applying dynamic furan‐maleimide Diels–Alder (DA) chemistry. The key step involves incorporating a furan group into the MOF via “click” PSM, which can then undergo repeated cycles of modification and de‐modification with maleimides. The structural integrity, crystallinity, and porosity of the furan‐appended MOF remained intact even after three consecutive PSM/de‐modification cycles using three different functionalized maleimides.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Reversible Postsynthetic Modification in a Metal–Organic Framework ; day:18 ; month:01 ; year:2024 ; extent:5
Angewandte Chemie ; (18.01.2024) (gesamt 5)

Urheber
Mondal, Prantik
Neuschuler, Zachary
Mandal, Dipendu
Hernandez, Ritchie E.
Cohen, Seth

DOI
10.1002/ange.202317062
URN
urn:nbn:de:101:1-2024011914161613181348
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:26 MESZ

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Beteiligte

  • Mondal, Prantik
  • Neuschuler, Zachary
  • Mandal, Dipendu
  • Hernandez, Ritchie E.
  • Cohen, Seth

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