Reversible Postsynthetic Modification in a Metal–Organic Framework

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Abstract: Postsynthetic modification (PSM) of metal–organic frameworks (MOFs) provides access to functional materials and advanced porous solid engineering. Herein, we report the reversible PSM of a multivariate isoreticular MOF by applying dynamic furan‐maleimide Diels–Alder (DA) chemistry. The key step involves incorporating a furan group into the MOF via “click” PSM, which can then undergo repeated cycles of modification and de‐modification with maleimides. The structural integrity, crystallinity, and porosity of the furan‐appended MOF remained intact even after three consecutive PSM/de‐modification cycles using three different functionalized maleimides.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Reversible Postsynthetic Modification in a Metal–Organic Framework ; day:18 ; month:01 ; year:2024 ; extent:5
Angewandte Chemie / International edition. International edition ; (18.01.2024) (gesamt 5)

Creator: Mondal, Prantik
Neuschuler, Zachary
Mandal, Dipendu
Hernandez, Ritchie E.
Cohen, Seth

DOI: 10.1002/anie.202317062

URN: urn:nbn:de:101:1-2024011914071488789166

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:32 AM CEST

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Associated

Mondal, Prantik
Neuschuler, Zachary
Mandal, Dipendu
Hernandez, Ritchie E.
Cohen, Seth

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