Sulfenyl Ynamides in Gold Catalysis: Synthesis of Oxo‐functionalised 4‐aminoimidazolyl Fused Compounds by Intermolecular Annulation Reactions
Abstract: Functionalised N‐heterocyclic pyridinium N‐aminides have been designed and synthesised to evaluate a nitrenoid‐based annulation strategy into imidazole‐fused oxo‐substituted frameworks of importance to medicinal and agrochemical discovery programmes. Sulfenyl substituted ynamides were identified as privileged reactants affording productive gold‐catalysed annulation reactions with these and other nitrenoids. This annulation method provides selective and efficient access into geminally amino‐sulfenyl substituted nitrogen heterocycles under mild reaction conditions.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Sulfenyl Ynamides in Gold Catalysis: Synthesis of Oxo‐functionalised 4‐aminoimidazolyl Fused Compounds by Intermolecular Annulation Reactions ; volume:362 ; number:12 ; year:2020 ; pages:2503-2509 ; extent:7
Advanced synthesis & catalysis ; 362, Heft 12 (2020), 2503-2509 (gesamt 7)
- Creator
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Arce, Elsa M.
Lamont, Scott G.
Davies, Paul W.
- DOI
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10.1002/adsc.202000134
- URN
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urn:nbn:de:101:1-2022060511520826635942
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:27 AM CEST
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Associated
- Arce, Elsa M.
- Lamont, Scott G.
- Davies, Paul W.
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