Structure–property relationship of polymerized ionic liquids for solid-state electrolyte membranes

Abstract: Eight new polymerized ammonium-based ionic liquids were prepared as thin membrane films and evaluated within the scope of their usage in lithium-ion batteries. The focus of this work is to get a better understanding of the influence of structural modifications of the monomers on the polymerized materials. Further, different concentrations of a lithium-ion conducting salt were applied in order to receive an optimized combination of monomer structure and lithium salt concentration. It was found that an increased side chain length of the studied ammonium-based polymerized ionic liquids leads to a reduction in glass transition temperatures and increased ionic conductivity values. As a result of the addition of conducting salt to the PIL membranes, the glass transition temperatures and the ionic conductivity values decreases. Nevertheless, PFG-NMR reveals a higher lithium-ion mobility for a sample with higher conducting salt content

Angaben zum Objekt

• Standort: Deutsche Nationalbibliothek Frankfurt am Main
• Umfang: Online-Ressource
• Sprache: Englisch
• Anmerkungen: Polymers. - 13, 5 (2021) , 792, ISSN: 2073-4360

Klassifikation und Themen

• Klassifikation: Elektrotechnik, Elektronik

Beteiligte, Orts- und Zeitangaben

• Ereignis: Veröffentlichung
• (wo): Freiburg
• (wer): Universität
• (wann): 2021
• Urheber: Löwe, Robert ; Hanemann, Thomas ; Zinkevich, Tatiana ; Hofmann, Andreas

Weitere Informationen

• DOI: 10.3390/polym13050792
• URN: urn:nbn:de:bsz:25-freidok-2204662
• Rechteinformation: Kein Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Letzte Aktualisierung: 15.08.2025, 07:26 MESZ