Total Synthesis, Stereochemical Assignment, and Divergent Enantioselective Enzymatic Recognition of Larreatricin
Abstract: A concise and efficient total synthesis of the lignan natural product larreatricin as well as an unambiguous assignment of configuration of its enantiomers are reported, resolving a long‐held controversy. Enzyme kinetic studies revealed that different polyphenol oxidases show high and remarkably divergent enantioselective recognition of this secondary metabolite.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Total Synthesis, Stereochemical Assignment, and Divergent Enantioselective Enzymatic Recognition of Larreatricin ; volume:24 ; number:59 ; year:2018 ; pages:15756-15760 ; extent:5
Chemistry - a European journal ; 24, Heft 59 (2018), 15756-15760 (gesamt 5)
- Urheber
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Martin, Harry J.
Kampatsikas, Ioannis
Oost, Rik
Pretzler, Matthias
Al‐Sayed, Emir
Roller, Alexander
Giester, Gerald
Rompel, Annette
Maulide, Nuno
- DOI
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10.1002/chem.201803785
- URN
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urn:nbn:de:101:1-2022082008165998535323
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:26 MESZ
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Beteiligte
- Martin, Harry J.
- Kampatsikas, Ioannis
- Oost, Rik
- Pretzler, Matthias
- Al‐Sayed, Emir
- Roller, Alexander
- Giester, Gerald
- Rompel, Annette
- Maulide, Nuno
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