Blue‐Light Driven Iron‐Catalyzed Oxy‐phosphinylation of Activated Alkenes for β‐Ketophosphine Oxide Synthesis
Abstract: We have developed an original blue‐light mediated iron‐catalyzed oxy‐phosphinylation of activated alkenes by secondary phosphine oxides under air at room temperature. Various β‐ketophosphine oxides were then obtained in 43–97 % isolated yields. Control experiments revealed that radical process is involved in the mechanism.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Blue‐Light Driven Iron‐Catalyzed Oxy‐phosphinylation of Activated Alkenes for β‐Ketophosphine Oxide Synthesis ; day:26 ; month:10 ; year:2023 ; extent:6
Chemistry - a European journal ; (26.10.2023) (gesamt 6)
- Creator
- DOI
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10.1002/chem.202302358
- URN
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urn:nbn:de:101:1-2023102715122888285154
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:48 AM CEST
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Associated
- Yuan, Yumeng
- Huang, Qiufeng
- Darcel, Christophe
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Iron-catalyzed carbonylation reactions
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Iron-catalyzed Hydrogenations of Olefins
Directed Iron-Catalyzed C–H Methylation
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Iron-catalyzed radical Markovnikov hydrohalogenation and hydroazidation of alkenes
Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay
Catalytic Oxy-aminomethylation of Alkenes
Iron-catalyzed carbonylation reactions
Cobalt-Catalyzed Reductive Coupling of Activated Alkenes with Alkynes
Iron-catalyzed Hydrogenations of Olefins
Directed Iron-Catalyzed C–H Methylation
Iron-Catalyzed Asymmetric OH Bond Insertions
Iron-Catalyzed Asymmetric Carboazidation of Styrenes
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