Iron‐Catalyzed, Light‐Driven Decarboxylative Oxygenation
Abstract: An iron‐catalyzed, visible light‐driven, dioxygen mediated decarboxylative oxygenation of carboxylic acids is disclosed. The catalytic system based on naturally existing Mohr salt and simple di (2‐picolyl) amine ligand is readily available and inexpensive. The applicability of the method was demonstrated through the efficient and selective synthesis of a range of ketones, aldehydes and amides including drug derivatives. Based on experimental investigations, a hypothetical mechanism was proposed.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Iron‐Catalyzed, Light‐Driven Decarboxylative Oxygenation ; day:24 ; month:10 ; year:2023 ; extent:9
European journal of organic chemistry ; (24.10.2023) (gesamt 9)
- Urheber
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Innocent, Milan
Lalande, Gabin
Cam, François
Aubineau, Thomas
Guérinot, Amandine
- DOI
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10.1002/ejoc.202300892
- URN
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urn:nbn:de:101:1-2023102415085357816631
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 10:54 MESZ
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Beteiligte
- Innocent, Milan
- Lalande, Gabin
- Cam, François
- Aubineau, Thomas
- Guérinot, Amandine
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