Preparation and chemical/microstructural characterization of azacrown ether-crosslinked chitosan films

Abstract: Chemically stable porous azacrown ether-crosslinked chitosan films were prepared by reacting varying molar amounts of N,N-diallyl-7,16-diaza-1,4,10,13-tetraoxa-dibenzo-18-crown-6 (molar equivalents ranging from 0, 0.125, 0.167, 0.25 and 0.5) with chitosan. Their chemical and structural properties were characterized by solid state-nuclear magnetic resonance (NMR), elemental, Fourier transform infrared (FTIR), microscopy, and X-ray analyses, as well as gel content. NMR and FTIR analyses of the reaction products suggested that new –CH2– crosslink bridges were produced between the amine groups of chitosan (Ch) and the allyl groups of the azacrown (DAC). The crosslinking chemistry between allyl and amine groups of the reactants was further evidenced with solution NMR studies on model compound of glucosamine with the azacrown. X-ray diffraction analysis of the Ch/azacrown films using wide angle X-ray scattering (WAXS), including synchrotron-WAXS, revealed that the crystalline arrangement of chitosan (Ch) was partially destroyed with increasing grafting of azacrown ether proportion on the Ch polymer chain. Solubility and gel content determination confirmed network formation with a gel content as high as 84–95 wt %. Microstructural analysis revealed microporous morphology with high surface area. The morphology and structure of the azacrown ether-crosslinked chitosan films could be tailored by stoichiometry of the reacting species

Angaben zum Objekt

• Standort: Deutsche Nationalbibliothek Frankfurt am Main
• Umfang: Online-Ressource
• Sprache: Englisch
• Anmerkungen: Materials. 10,4 (2017), 400. DOI 10.3390/ma10040400, issn: 1996-1944 ; cc_by http://creativecommons.org/licenses/by/4.0/deed.de cc

Klassifikation und Themen

• Klassifikation: Chemie
• Schlagwort: Chitosan ; Adsorption

Beteiligte, Orts- und Zeitangaben

• Ereignis: Veröffentlichung
• (wo): Freiburg
• (wer): Universität
• (wann): 2017
• Urheber: Toeri, Julius Ratumo ; Osorio-Madrazo, Anayancy ; Laborie, Marie-Pierre
• Beteiligte Personen und Organisationen: Freiburger Materialforschungszentrum ; Professur für Forstliche Biomaterialien ; Technische Fakultät ; Professur für Sensoren ; Albert-Ludwigs-Universität Freiburg

Weitere Informationen

• DOI: 10.3390/ma10040400
• URN: urn:nbn:de:bsz:25-freidok-123327
• Rechteinformation: Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Letzte Aktualisierung: 25.03.2025, 13:55 MEZ