Visualizing Penetration of Fluorescent Dye through Polymer Coatings

Abstract: Understanding how small molecules penetrate and contaminate polymer films is of vital importance for developing protective coatings for a wide range of applications. To this end, rhodamine B fluorescent dye is visualized diffusing through polystyrene‐polydimethylsiloxane block copolymer (BCP) coatings using confocal microscopy. The intensity of dye inside the coatings grows and decays non‐monotonically, which is likely due to a combination of dye molecule transport occurring concurrently in different directions. An empirical fitting equation allows for comparing the contamination rates between copolymers, demonstrating that dye penetration is related to the chemical makeup and configuration of the BCPs. This work shows that confocal microscopy can be a useful tool to visualize the transport of a fluorophore in space and time through a coating.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Visualizing Penetration of Fluorescent Dye through Polymer Coatings ; day:21 ; month:08 ; year:2023 ; extent:9
Macromolecular rapid communications ; (21.08.2023) (gesamt 9)

Creator
Chaudhuri, Krishnaroop
Medhi, Riddhiman
Zhang, Zhenglin
Cai, Zhuoyun
Ober, Christopher K.
Pham, Jonathan T.

DOI
10.1002/marc.202300304
URN
urn:nbn:de:101:1-2023082215222937313814
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:45 AM CEST

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Associated

  • Chaudhuri, Krishnaroop
  • Medhi, Riddhiman
  • Zhang, Zhenglin
  • Cai, Zhuoyun
  • Ober, Christopher K.
  • Pham, Jonathan T.

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