Crystalline Germanium (I) and Tin (I) Centered Radical Anions
Abstract: An isostructural series of heavy Group 14 E (I) radical anions (Ge, Sn, Pb), stabilized by a bulky xanthene‐based diamido ligand are reported. The radical anions were synthesised by the one‐electron reduction of their corresponding E (II) precursor complexes with sodium naphthalenide in THF, yielding the radical anions as charge‐separated sodium salts. The series of main group radicals have been comprehensively characterized by EPR spectroscopy, X‐ray crystallography and DFT analysis, which reveal that in all cases, the spin density of the unpaired electron almost exclusively resides in a p‐orbital of π symmetry located on the Group 14 center.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Crystalline Germanium (I) and Tin (I) Centered Radical Anions ; day:23 ; month:03 ; year:2022 ; extent:1
Angewandte Chemie ; (23.03.2022) (gesamt 1)
- Urheber
-
Lim, Li Feng
Judd, Martyna
Vasko, Petra
Gardiner, Michael G.
Pantazis, Dimitrios A.
Cox, Nicholas
Hicks, Jamie
- DOI
-
10.1002/ange.202201248
- URN
-
urn:nbn:de:101:1-2022032514054694821510
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:32 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Lim, Li Feng
- Judd, Martyna
- Vasko, Petra
- Gardiner, Michael G.
- Pantazis, Dimitrios A.
- Cox, Nicholas
- Hicks, Jamie
Ähnliche Objekte (12)
Crystalline Germanium (I) and Tin (I) Centered Radical Anions
Photoemission from tin and lead cluster anions
Tin diffusion in germanium: a thermodynamic approach
Crystalline anions based on classical N‐heterocyclic carbenes
Crystalline Anions Based on Classical N‐Heterocyclic Carbenes
Single‐Crystalline Colloidal Quasi‐2D Tin Telluride
Organometallic Compounds, Vol. 2.. Organic compounds of germanium, tin and lead
Experimental studies on germanium-tin p-channel tunneling field effect transistors
Revealing Low Thermal Conductivity of Germanium Tin Semiconductor at Room Temperature
Synthesis and Characterization of New Low-Valent Silicon, Germanium and Tin Compounds
Efficient In Situ Doping of Strained Germanium Tin Epilayers at Unusually Low Temperature
Scalable, Template Driven Formation of Highly Crystalline Lead‐Tin Halide Perovskite Films
Crystalline Germanium (I) and Tin (I) Centered Radical Anions
Photoemission from tin and lead cluster anions
Tin diffusion in germanium: a thermodynamic approach
Crystalline anions based on classical N‐heterocyclic carbenes
Crystalline Anions Based on Classical N‐Heterocyclic Carbenes
Single‐Crystalline Colloidal Quasi‐2D Tin Telluride
Organometallic Compounds, Vol. 2.. Organic compounds of germanium, tin and lead
Experimental studies on germanium-tin p-channel tunneling field effect transistors
Revealing Low Thermal Conductivity of Germanium Tin Semiconductor at Room Temperature
Synthesis and Characterization of New Low-Valent Silicon, Germanium and Tin Compounds
Efficient In Situ Doping of Strained Germanium Tin Epilayers at Unusually Low Temperature
Scalable, Template Driven Formation of Highly Crystalline Lead‐Tin Halide Perovskite Films
Crystalline Germanium (I) and Tin (I) Centered Radical Anions
Photoemission from tin and lead cluster anions
Tin diffusion in germanium: a thermodynamic approach
Crystalline anions based on classical N‐heterocyclic carbenes
Crystalline Anions Based on Classical N‐Heterocyclic Carbenes
Single‐Crystalline Colloidal Quasi‐2D Tin Telluride
Organometallic Compounds, Vol. 2.. Organic compounds of germanium, tin and lead
Experimental studies on germanium-tin p-channel tunneling field effect transistors
Revealing Low Thermal Conductivity of Germanium Tin Semiconductor at Room Temperature
Synthesis and Characterization of New Low-Valent Silicon, Germanium and Tin Compounds
Efficient In Situ Doping of Strained Germanium Tin Epilayers at Unusually Low Temperature