Mechanistic Studies on Trichoacorenol Synthase from Amycolatopsis benzoatilytica
Abstract: Isotopic labeling experiments performed with a newly identified bacterial trichoacorenol synthase established a 1,5‐hydride shift occurring in the cyclization mechanism. During EI‐MS analysis, major fragments of the sesquiterpenoid were shown to arise via cryptic hydrogen movements. Therefore, the interpretation of earlier results regarding the cyclization mechanism obtained by feeding experiments in Trichoderma is revised.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Mechanistic Studies on Trichoacorenol Synthase from Amycolatopsis benzoatilytica ; volume:21 ; number:6 ; year:2020 ; pages:807-810 ; extent:4
ChemBioChem ; 21, Heft 6 (2020), 807-810 (gesamt 4)
- Urheber
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Rinkel, Jan
Dickschat, Jeroen S.
- DOI
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10.1002/cbic.201900584
- URN
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urn:nbn:de:101:1-2022061806270848876035
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:24 MESZ
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Beteiligte
- Rinkel, Jan
- Dickschat, Jeroen S.
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