Fragmentation of Ammonium Nitrate Particles under Thermal Cycling

Abstract: Ammonium nitrate finds application in explosives and chlorine‐free slow‐burning propellants. Different phases are known for this ammonium salt, each of them featured by peculiar bulk densities. As a consequence, the variation of storage temperature induces processes of expansion‐contraction in the crystals, unless specific stabilization is performed. In this paper, a batch of raw ammonium nitrate particles has been thermally cycled between −30 °C to +60 °C and analyzed. Microscopic observations, particle size measurement, and X‐ray microtomography showed that the particles undergo a progressive fragmentation process, with opening of internal cracks and voids. The tested material halved its mass‐mean diameter after five thermal cycles. As a term of comparison, a phase‐stabilized ammonium nitrate batch was tested under the same conditions, showing no effect.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Fragmentation of Ammonium Nitrate Particles under Thermal Cycling ; volume:43 ; number:3 ; year:2018 ; pages:315-319 ; extent:5
Propellants, explosives, pyrotechnics ; 43, Heft 3 (2018), 315-319 (gesamt 5)

Creator
Maggi, Filippo
Garg, Priya

DOI
10.1002/prep.201700230
URN
urn:nbn:de:101:1-2022091107520115788670
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:35 AM CEST

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Associated

  • Maggi, Filippo
  • Garg, Priya

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