Lab‐Scale Demonstration of By‐Product Utilization in an Integrated Power‐to‐Liquid Process Applying Co‐Electrolysis

High‐temperature electrolysis has been shown to be a promising technology for the so‐called Power‐to‐Liquid processes. However, to reach the full potential of high‐temperature electrolysis regarding process efficiency, by‐product recirculation and heat utilization are of vital importance. Herein, the possibility to perform internal reforming of by‐products within the electrolyzer to again obtain syngas can be advantageous. This mode of operation is demonstrated in electrolysis lab tests on cell and stack level, showing the ability to convert methane. However, the recycled gaseous product stream from a Fischer–Tropsch synthesis is much broader in its composition and longer‐chained hydrocarbons may lead to issues such as carbon formation, thermal stress, and catalytic stability. Herein, the Power‐to‐Liquid process, consisting of high‐temperature co‐electrolysis and Fischer–Tropsch synthesis, is implemented in a laboratory‐scale plant to study the possibility of internally reforming by‐products within the electrolyzer. Herein, the importance of by‐product recirculation is highlighted by the results of the investigation, as it allows for a significant increase in carbon efficiency and subsequently in energetic efficiency, but especially the potential of high‐temperature electrolysis for integrated process concepts applying internal reforming.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Lab‐Scale Demonstration of By‐Product Utilization in an Integrated Power‐to‐Liquid Process Applying Co‐Electrolysis ; day:24 ; month:02 ; year:2023 ; extent:11
Energy technology ; (24.02.2023) (gesamt 11)

Urheber
Herz, Gregor
Gallwitz, Michael
Näke, Ralf
Megel, Stefan
Jahn, Matthias
Reichelt, Erik

DOI
10.1002/ente.202201057
URN
urn:nbn:de:101:1-2023022814015310896142
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
14.08.2025, 10:49 MESZ

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Beteiligte

  • Herz, Gregor
  • Gallwitz, Michael
  • Näke, Ralf
  • Megel, Stefan
  • Jahn, Matthias
  • Reichelt, Erik

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