Exploring Ferrocenyl Imine‐Phosphane Complexes in Gold (I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant

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Abstract: Another class of gold (I) redox‐switchable catalysts, incorporating ferrocenyl phosphane‐imines, enriches the existing library of gold (I) complexes. Our catalyst proves efficacy in gold (I)‐catalyzed cyclizations of furans and benzamides, exhibiting reversible “on‐off” switching. Furthermore, we explored the unconventional role of “Magic Blue”, commonly used as an oxidizing agent in various organic transformations, as a potential activator of the Au−Cl bond, initiating conventional gold (I) catalysis.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Exploring Ferrocenyl Imine‐Phosphane Complexes in Gold (I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant ; day:06 ; month:08 ; year:2024 ; extent:9
Advanced synthesis & catalysis ; (06.08.2024) (gesamt 9)

Urheber
Pérez‐Sánchez, Juan Carlos
Herrera, Raquel P.
Gimeno, M. Concepción

DOI
10.1002/adsc.202400593
URN
urn:nbn:de:101:1-2408071422282.180580950118
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
14.08.2025, 10:46 MESZ

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