Exploring Ferrocenyl Imine‐Phosphane Complexes in Gold (I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant

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Abstract: Another class of gold (I) redox‐switchable catalysts, incorporating ferrocenyl phosphane‐imines, enriches the existing library of gold (I) complexes. Our catalyst proves efficacy in gold (I)‐catalyzed cyclizations of furans and benzamides, exhibiting reversible “on‐off” switching. Furthermore, we explored the unconventional role of “Magic Blue”, commonly used as an oxidizing agent in various organic transformations, as a potential activator of the Au−Cl bond, initiating conventional gold (I) catalysis.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Exploring Ferrocenyl Imine‐Phosphane Complexes in Gold (I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant ; day:06 ; month:08 ; year:2024 ; extent:9
Advanced synthesis & catalysis ; (06.08.2024) (gesamt 9)

Creator: Pérez‐Sánchez, Juan Carlos
Herrera, Raquel P.
Gimeno, M. Concepción

DOI: 10.1002/adsc.202400593

URN: urn:nbn:de:101:1-2408071422282.180580950118

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 14.08.2025, 10:46 AM CEST

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Pérez‐Sánchez, Juan Carlos
Herrera, Raquel P.
Gimeno, M. Concepción

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Exploring Ferrocenyl Imine‐Phosphane Complexes in Gold (I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant

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Other Objects (12)

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Ferrocenyl Dinuclear Gold (I) Complexes. Study of their Structural Features and the Influence of Bridging and Phosphane Ligands in a Catalytic Cyclization Reaction

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Switchable, Reagent‐Controlled Diastereodivergent Photocatalytic Carbocyclisation of Imine‐Derived α‐Amino Radicals

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