Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials
Abstract: A new method of supramolecular polymerization at the water–oil interface is developed. As a demonstration, an oil‐soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water‐soluble monomer bearing two maleimide end groups are employed. Supramolecular interfacial polymerization can be implemented by a thiol–maleimide click reaction at the water–chloroform interface to obtain supramolecular polymeric films. The glass transition temperature of such supramolecular polymers can be well‐tuned by simply changing the polymerization time and temperature. It is highly anticipated that this work will provide a facile and general approach to realize control over supramolecular polymerization by transferring the preparation of supramolecular polymers from solutions to water–oil interfaces and construct supramolecular materials with well‐defined properties.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials ; volume:129 ; number:26 ; year:2017 ; pages:7747-7751 ; extent:5
Angewandte Chemie ; 129, Heft 26 (2017), 7747-7751 (gesamt 5)
- Urheber
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Qin, Bo
Zhang, Shuai
Song, Qiao
Huang, Zehuan
Xu, Jiang‐Fei
Zhang, Xi
- DOI
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10.1002/ange.201703572
- URN
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urn:nbn:de:101:1-2022091406564193149126
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:28 MESZ
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Beteiligte
- Qin, Bo
- Zhang, Shuai
- Song, Qiao
- Huang, Zehuan
- Xu, Jiang‐Fei
- Zhang, Xi
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